Materials Map

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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Kociok-Köhn, Gabriele

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University of Bath

in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (38/38 displayed)

  • 2024Understanding and tuning the electronic structure of pentalenides3citations
  • 2024Synthesis and Structure of Heavy Alkali Metal Pentalenidescitations
  • 2023Variations around the presence and position of sulfur in sugar-derived cyclic monomers: influence on polymerisation thermodynamics, polymer sequence and thermal properties8citations
  • 2023Structural and Functional Diversity in Rigid Thiosemicarbazones with Extended Aromatic Frameworks1citations
  • 2022Diaminopyridine Hg(II)-based 1D supramolecular polymer8citations
  • 2022Ferrocene Appended Asymmetric Sensitizers with Azine Spacers with phenolic/nitro anchors for Dye-Sensitized Solar Cells11citations
  • 2022N-O Ligand Supported Stannylenes2citations
  • 2021Structural Investigations, Cellular Imaging, and Radiolabeling of Neutral, Polycationic, and Polyanionic Functional Metalloporphyrin Conjugates15citations
  • 2019Aerosol-Assisted Chemical Vapor Deposition of ZnS from Thioureide Single Source Precursors22citations
  • 2019Divergent Catalytic Strategies for the Cis/Trans Stereoselective Ring-Opening Polymerization of a Dual Cyclic Carbonate/Olefin Monomer62citations
  • 2019Influence of ligand coordination, solvent, and non-covalent interaction on the structural outcomes in coordination polymers with direct Cd(II)-alkanesulfonate bonds9citations
  • 2019Quantitative resonant soft x-ray reflectivity from an organic semiconductor single crystal4citations
  • 2019Directed Molecular Stacking for Engineered Fluorescent Three-Dimensional Reduced Graphene Oxide and Coronene Frameworks5citations
  • 2018Synthesis, Characterisation and Thermal Properties of Sn(II) Pyrrolide Complexes14citations
  • 2018Bipyrrolidine salan alkoxide complexes of lanthanides: synthesis, characterisation, activity in the polymerisation of lactide and mechanistic investigation by DOSY NMR8citations
  • 2017Polymers from sugars and CO271citations
  • 2016A study on the AMACR catalysed elimination reaction and its application to inhibitor testing11citations
  • 2016Homoleptic zirconium amidates16citations
  • 2016Transition metal ferrocenyl dithiocarbamates functionalized dye-sensitized solar cells with hydroxy as an anchoring group29citations
  • 2015Tailoring precursors for deposition10citations
  • 2015Synthesis and optical properties of biphenylene ethynylene co-polymers and their model compounds2citations
  • 2015Synthesis and characterization of fluorinated β-ketoiminate zinc precursors and their utility in the AP-MOCVD growth of ZnO:F16citations
  • 2014Preparation of stereoregular isotactic poly(mandelic acid) through organocatalytic ring-opening polymerization of a cyclic O-carboxyanhydride95citations
  • 2014The first crystallographically-characterised Cu(II) xanthate14citations
  • 2013Synthesis of heterobimetallic tungsten acetylacetonate/alkoxide complexes and their application as molecular precursors to metal tungstates5citations
  • 2013Synthesis and structural characterization of group 4 metal alkoxide complexes of N, N, N ′,N ′-tetrakis(2-hydroxyethyl)ethylenediamine and their use as initiators in the ring-opening polymerization (ROP) of rac -lactide under industrially relevant conditions30citations
  • 2013Synthesis, spectroscopic characterization and crystal and molecular structures of phenylphosphonato SnR3 (R=Ph, Me) derivatives2citations
  • 2013Inorganic and organozinc fluorocarboxylates9citations
  • 2011Homopiperazine and piperazine complexes of Zr(IV) and Hf(IV) and their application to the ring-opening polymerisation of lactide34citations
  • 2010CuInSe2 precursor films electro-deposited directly onto MoSe28citations
  • 2010The synthesis and reaction chemistry of new amino-functionalised tin(ii) alkoxides6citations
  • 2009Novel Ti(IV) and Zr(IV) complexes and their application in the ring-opening polymerisation of cyclic esters59citations
  • 2008Deposition and characterization of ZnO thin films from a novel hexanuclear zinc precursor23citations
  • 2008Copper-cobalt heterobimetallic ceramic oxide thin film deposition: Synthesis, characterization and application of precursor22citations
  • 2006Synthesis, thermal decomposition pattern and single crystal X-ray studies of dimeric [Cu(dmae)(OCOCH3)(H2O)](2): A precursor for the aerosol assisted chemical vapour deposition of copper metal thin filmscitations
  • 2005Synthesis and structural characterization of a new heterobimetallic coordination complex of barium and cobalt for use as a precursor for chemical vapor deposition30citations
  • 2005A new series of luminescent phosphine stabilised platinum ethynyl complexes38citations
  • 2003exo-closo-rhodacarboranes: synthesis and characterisation of [{exo-(R3P)(2)Rh}(closo-CB11H12)][R3P = P(OMe)(3), PCy3, 1/2dppe]16citations

Places of action

Chart of shared publication
Helten, Holger
1 / 1 shared
Helbig, Andreas
1 / 1 shared
Jenek, Niko A.
1 / 1 shared
Hintermair, Ulrich
2 / 6 shared
Reeksting, Shaun B.
1 / 1 shared
Kaur, Mandeep
1 / 7 shared
Sanderson, Hugh J.
1 / 1 shared
Boyt, Stuart M.
1 / 1 shared
Sanderson, Hugh
1 / 1 shared
Kennedy, Alan R.
1 / 10 shared
Robertson, Stuart D.
1 / 1 shared
Banerjee, Sumanta
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Hardy, Craig
1 / 1 shared
Buchard, Antoine
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Dilworth, Jonathan R.
2 / 3 shared
Cortezon-Tamarit, Fernando
3 / 3 shared
Ge, Haobo
2 / 2 shared
Arrowsmith, Rory L.
1 / 1 shared
Kuganathan, Navaratnarajah
2 / 6 shared
Song, Kexin
1 / 1 shared
Shanmugam, Muralidharan
1 / 1 shared
Collison, David
1 / 13 shared
Aguiar, Sara M. M. De
1 / 1 shared
Waghorn, Philip A.
2 / 2 shared
Pascu, Sofia
3 / 8 shared
Pourzand, Charareh
1 / 1 shared
Brookfield, Adam
1 / 8 shared
Muddassir, Mohd
2 / 2 shared
Dutta, Archisman
1 / 2 shared
Kumar, Abhinav
3 / 9 shared
Singh, Amita
2 / 2 shared
Gosavi, Suresh W.
1 / 1 shared
Chauhan, Ratna
2 / 3 shared
Johnson, Andrew L.
9 / 40 shared
Sullivan, Hannah
2 / 4 shared
Straiton, Andrew
1 / 1 shared
Botchway, Stanley W.
2 / 4 shared
Ge, Haobe
1 / 1 shared
Ciaffaglione, Valeria
1 / 1 shared
Exner, Rudiger M.
1 / 1 shared
Sarpaki, Sophia
1 / 1 shared
Godfrey, Samuel P.
1 / 1 shared
Dondi, Ruggero
1 / 1 shared
Quilter, Helen
1 / 1 shared
Eggleston, Ian
1 / 1 shared
Hill, Michael S.
4 / 17 shared
Thongchai, Prem
1 / 2 shared
Parish, James
2 / 11 shared
Castaing, Rémi
2 / 2 shared
Pérale, Cécile
1 / 1 shared
Mcguire, Thomas M.
1 / 2 shared
Singh, Rohit
1 / 3 shared
Singh, Kaman
1 / 2 shared
Singh, Larisa
1 / 1 shared
Pandey, Sarvesh Kumar
1 / 1 shared
Capelli, R.
1 / 2 shared
Pasquali, L.
1 / 3 shared
Fontanesi, C.
1 / 13 shared
Como, Enrico Da
1 / 6 shared
Verna, A.
1 / 9 shared
Mao, Boyang
1 / 8 shared
Mirabello, Vincenzo
1 / 4 shared
Palomares, Francisco J.
1 / 1 shared
Calatayud, David G.
1 / 8 shared
Snook, Michael W.
1 / 2 shared
Beament, James
1 / 2 shared
Jones, Matthew D.
3 / 18 shared
Gregory, Georgina L.
1 / 1 shared
Sun, Xiaolong
1 / 1 shared
James, Tony D.
1 / 7 shared
Woodman, Timothy
1 / 5 shared
Sun, Jenny
1 / 1 shared
Zhou, Shiyi
1 / 1 shared
Jevglevskis, Maksims
1 / 1 shared
Lloyd, Matthew
1 / 1 shared
Lee, Guat Ling
1 / 1 shared
Mahon, Mary F.
4 / 22 shared
Catherall, Amanda L.
1 / 2 shared
Waghadkar, Yogesh
1 / 1 shared
Yadav, Reena
1 / 4 shared
Rane, Sunit B.
1 / 1 shared
Sung, S. L.
1 / 2 shared
Williams, P. A.
1 / 2 shared
Cosham, S. D.
1 / 2 shared
Heil, T.
1 / 5 shared
Chalker, P. R.
1 / 5 shared
Pugh, Thomas
1 / 4 shared
Willcocks, Alex
1 / 2 shared
Hamilton, J.
1 / 3 shared
Begum, Rockshana
1 / 1 shared
Debnath, Dipen
1 / 1 shared
Anis-Ul-Haque, Kazi M.
1 / 1 shared
Nag, Okhil K.
1 / 1 shared
Chawdhury, Nazia
1 / 1 shared
Younus, Muhammad
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Raithby, Paul R.
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Molloy, Kieran C.
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Hamilton, Jeff A.
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Cosham, Samuel D.
1 / 6 shared
Davidson, Matthew G.
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Jeffery, Ben J.
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Carbery, David R.
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Ivanova, Petya K.
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Lowe, John P.
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Sudlow, A. L.
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Molloy, K. C.
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Choujaa, H.
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Manton, Lois B.
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Sart, Gerrit Gobius Du
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Ivanova-Mitseva, Petya K.
1 / 1 shared
Chuck, Christopher
1 / 3 shared
Diop, Tidiane
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Ardisson, Jose Domingos
1 / 1 shared
Diop, Libasse
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Kingsley, A. J.
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Hancock, Stuart L.
1 / 1 shared
Zoppi, Guillaume
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Marken, Frank
1 / 91 shared
Cummings, Charles
1 / 1 shared
Peter, Laurence M.
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Dale, Phillip
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Scragg, Jonathan J.
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Forbes, Ian
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Hollingsworth, Nathan
1 / 1 shared
Sudlow, Anna L.
1 / 1 shared
Whitelaw, E. L.
1 / 1 shared
Tahir, A. A.
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Ahmad, F.
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Hamid, M.
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Mazhar, M.
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Rabbani, F.
1 / 1 shared
Hussain, S. M.
1 / 1 shared
Dastgir, S.
1 / 2 shared
Ooi, L. L.
1 / 2 shared
Kijima, M.
1 / 1 shared
Chawdhury, N.
1 / 2 shared
Sultana, N.
1 / 3 shared
Younus, M.
1 / 2 shared
Debnath, D.
1 / 1 shared
Qaium, M. A.
1 / 1 shared
Saha, R.
1 / 7 shared
Laing, V. E.
1 / 1 shared
Weller, A. S.
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Ruggiero, G. D.
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Chart of publication period
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2019
2018
2017
2016
2015
2014
2013
2011
2010
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Co-Authors (by relevance)

  • Helten, Holger
  • Helbig, Andreas
  • Jenek, Niko A.
  • Hintermair, Ulrich
  • Reeksting, Shaun B.
  • Kaur, Mandeep
  • Sanderson, Hugh J.
  • Boyt, Stuart M.
  • Sanderson, Hugh
  • Kennedy, Alan R.
  • Robertson, Stuart D.
  • Banerjee, Sumanta
  • Hardy, Craig
  • Buchard, Antoine
  • Dilworth, Jonathan R.
  • Cortezon-Tamarit, Fernando
  • Ge, Haobo
  • Arrowsmith, Rory L.
  • Kuganathan, Navaratnarajah
  • Song, Kexin
  • Shanmugam, Muralidharan
  • Collison, David
  • Aguiar, Sara M. M. De
  • Waghorn, Philip A.
  • Pascu, Sofia
  • Pourzand, Charareh
  • Brookfield, Adam
  • Muddassir, Mohd
  • Dutta, Archisman
  • Kumar, Abhinav
  • Singh, Amita
  • Gosavi, Suresh W.
  • Chauhan, Ratna
  • Johnson, Andrew L.
  • Sullivan, Hannah
  • Straiton, Andrew
  • Botchway, Stanley W.
  • Ge, Haobe
  • Ciaffaglione, Valeria
  • Exner, Rudiger M.
  • Sarpaki, Sophia
  • Godfrey, Samuel P.
  • Dondi, Ruggero
  • Quilter, Helen
  • Eggleston, Ian
  • Hill, Michael S.
  • Thongchai, Prem
  • Parish, James
  • Castaing, Rémi
  • Pérale, Cécile
  • Mcguire, Thomas M.
  • Singh, Rohit
  • Singh, Kaman
  • Singh, Larisa
  • Pandey, Sarvesh Kumar
  • Capelli, R.
  • Pasquali, L.
  • Fontanesi, C.
  • Como, Enrico Da
  • Verna, A.
  • Mao, Boyang
  • Mirabello, Vincenzo
  • Palomares, Francisco J.
  • Calatayud, David G.
  • Snook, Michael W.
  • Beament, James
  • Jones, Matthew D.
  • Gregory, Georgina L.
  • Sun, Xiaolong
  • James, Tony D.
  • Woodman, Timothy
  • Sun, Jenny
  • Zhou, Shiyi
  • Jevglevskis, Maksims
  • Lloyd, Matthew
  • Lee, Guat Ling
  • Mahon, Mary F.
  • Catherall, Amanda L.
  • Waghadkar, Yogesh
  • Yadav, Reena
  • Rane, Sunit B.
  • Sung, S. L.
  • Williams, P. A.
  • Cosham, S. D.
  • Heil, T.
  • Chalker, P. R.
  • Pugh, Thomas
  • Willcocks, Alex
  • Hamilton, J.
  • Begum, Rockshana
  • Debnath, Dipen
  • Anis-Ul-Haque, Kazi M.
  • Nag, Okhil K.
  • Chawdhury, Nazia
  • Younus, Muhammad
  • Raithby, Paul R.
  • Molloy, Kieran C.
  • Hamilton, Jeff A.
  • Cosham, Samuel D.
  • Davidson, Matthew G.
  • Jeffery, Ben J.
  • Carbery, David R.
  • Ivanova, Petya K.
  • Lowe, John P.
  • Sudlow, A. L.
  • Molloy, K. C.
  • Choujaa, H.
  • Manton, Lois B.
  • Sart, Gerrit Gobius Du
  • Ivanova-Mitseva, Petya K.
  • Chuck, Christopher
  • Diop, Tidiane
  • Ardisson, Jose Domingos
  • Diop, Libasse
  • Kingsley, A. J.
  • Hancock, Stuart L.
  • Zoppi, Guillaume
  • Marken, Frank
  • Cummings, Charles
  • Peter, Laurence M.
  • Dale, Phillip
  • Scragg, Jonathan J.
  • Forbes, Ian
  • Hollingsworth, Nathan
  • Sudlow, Anna L.
  • Whitelaw, E. L.
  • Tahir, A. A.
  • Ahmad, F.
  • Hamid, M.
  • Mazhar, M.
  • Rabbani, F.
  • Hussain, S. M.
  • Dastgir, S.
  • Ooi, L. L.
  • Kijima, M.
  • Chawdhury, N.
  • Sultana, N.
  • Younus, M.
  • Debnath, D.
  • Qaium, M. A.
  • Saha, R.
  • Laing, V. E.
  • Weller, A. S.
  • Ruggiero, G. D.
  • Rifat, A.
OrganizationsLocationPeople

article

Bipyrrolidine salan alkoxide complexes of lanthanides: synthesis, characterisation, activity in the polymerisation of lactide and mechanistic investigation by DOSY NMR

  • Kociok-Köhn, Gabriele
  • Beament, James
  • Jones, Matthew D.
  • Buchard, Antoine
Abstract

<p>Four dimeric lanthanide alkoxide complexes bearing ONNO bipyrrolidine salan ligands (L<sup>Me</sup>H<sub>2</sub>/L<sup>tBu</sup>H<sub>2</sub>) have been prepared with Nd, Sm and Yb. Depending on the metal and substituents, these complexes adopt varying coordination geometries. While investigating the hydrolytic degradation of these complexes, three dimeric mixed alkoxide/hydroxide and bis-hydroxide products were also prepared, isolated and characterised. Despite paramagnetism,<sup>1</sup>H NMR and diffusion ordered spectroscopy (DOSY) allowed additional characterisation alongside elemental and single-crystal X-ray diffraction analyses. These systems were very active for the controlled ring-opening polymerisation (ROP) of rac-lactide (LA), under industrially relevant melt conditions and in solution, yielding complete conversion within 5 minutes at [Ln]:[LA] ratios of up to 3000:1 in toluene, and at 80 °C, whilst retaining low dispersities (D = 1.1).<sup>1</sup>H DOSY NMR spectroscopy was employed to monitor polymer growth from the metal centres in situ, and revealed a dinuclear catalytically active species.</p>

Topics
  • polymer
  • x-ray diffraction
  • melt
  • Nuclear Magnetic Resonance spectroscopy
  • Lanthanide