| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Shaver, Michael P.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (28/28 displayed)
- 2024Performance polyamides built on a sustainable carbohydrate corecitations
- 2024Mechanical Properties and Recyclability of Fibre Reinforced Polyester Compositescitations
- 2023Degradable and Reprocessable Resins from a Dioxolanone Cross-Linkercitations
- 2023Understanding poly(ethylene terephthalate) degradation using gas-mediated simulated recyclingcitations
- 2020Mechanical Recycling of Packaging Plastics: A Reviewcitations
- 2018Polymeric hole-transport materials with side-chain redox-active groups for perovskite solar cells with good reproducibilitycitations
- 2018Polymeric hole-transport materials with side-chain redox-active groups for perovskite solar cells with good reproducibilitycitations
- 2018Thermal, optical and structural properties of blocks and blends of PLA and P2HEBcitations
- 2018Functionalizable Stereocontrolled Cyclopolyethers by Ring-Closing Metathesis as Natural Polymer Mimicscitations
- 2018Morphology of Poly(styrene-co-butadiene) Random Copolymer Thin Films and Nanostructures on a Graphite Surfacecitations
- 2017Thermal, structural and degradation properties of an aromatic-aliphatic polyester built through ring-opening polymerisationcitations
- 2017Poly(styrene-co-butadiene) Random Copolymer Thin Films and Nanostructures on a Mica Surface: Morphology and Contact Angles of Nanodropletscitations
- 2017Olefin cross metathesis and ring-closing metathesis in polymer chemistrycitations
- 2016Installing Multiple Functional Groups on Biodegradable Polyesters via Post-Polymerization Olefin Cross-Metathesiscitations
- 2015Aluminum Salen and Salan Polymerization Catalystscitations
- 2014Tuning ligand electronics and peripheral substitution on cobalt salen complexes:Structure and polymerisation activitycitations
- 2014Tuning ligand electronics and peripheral substitution on cobalt salen complexescitations
- 2013Aluminium salophen and salen initiators in the ring-opening polymerisation of rac-lactide and rac-β-butyrolactone::Electronic effects on stereoselectivity and polymerisation ratescitations
- 2013Poly(lactic acid) polymer stars built from early generation dendritic polyolscitations
- 2013Tacticity-induced changes in the micellization and degradation properties of poly(lactic acid)-block-poly(ethylene glycol) copolymerscitations
- 2013Aluminium salophen and salen initiators in the ring-opening polymerisation of rac-lactide and rac-β-butyrolactone:citations
- 2012Control of thermal properties and hydrolytic degradation in poly(lactic acid) polymer stars through control of isospecificity of polymer armscitations
- 2012Anilido-aldimine aluminum complexes:citations
- 2012Controlled radical polymerization mediated by Amine-Bis(phenolate) Iron(III) complexescitations
- 2012Anilido-aldimine aluminum complexes::Synthesis, characterization and lactide polymerizationcitations
- 2010Tacticity control in the synthesis of poly(lactic acid) polymer stars with dipentaerythritol corescitations
- 20084.4,5,5-tetraphenyl-1,3,2-dioxaborolanecitations
- 2000Trans alkenylpyridine and alkenylamine complexes of platinum
Places of action
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article
Polymeric hole-transport materials with side-chain redox-active groups for perovskite solar cells with good reproducibility
Abstract
Two monomers, M:OO and M:ON, and their corresponding polymers, P:OO and P:ON, were prepared from styrene derivatives N,N-diphenyl-4-vinyl-aniline with different substitutents (-OCH3 and –N(CH3)2) in the N-phenyl para positions. The polymers were synthesised and fully characterised to study their function as hole transport materials (HTMs) in perovskite solar cells (PSCs). The thermal, optical and electrochemical properties and performance of these monomers and polymers as HTMs in PSCs were compared in terms of their structure. The polymers form more stable amorphous glassy states and showed higher thermal stability than the monomers. The different substituent in the para position influenced the highest occupied molecular orbital (HOMO) level, altering the oxidation potential. Both monomers and polymers were employed as HTMs in perovskite solar cells with a device configuration FTO/bl-TiO2/mp-TiO2/CH3NH3PbI3/HTM/Au resulting in power conversion efficiencies of 7.48% for M:OO, 5.14% for P:OO, 5.28% for P:ON and 3.52% for M:ON. Although showing comparatively low efficiencies, the polymers showed much superior reproducibility in comparison with Spiro-OMeTAD or the monomers, suggesting further optimisation of polymeric HTMs with redox side groups is warranted.