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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Worrall, Stephen D.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Block copolymer synthesis in ionic liquid via polymerisation-induced self-assembly: A convenient route to gel electrolytescitations
- 2018Anodic dissolution growth of metal-organic framework HKUST-1 monitored:Via in situ electrochemical atomic force microscopy
- 2018Anodic dissolution growth of metal-organic framework HKUST-1 monitored via in situ electrochemical atomic force microscopycitations
- 2018Anodic dissolution growth of metal-organic framework HKUST-1 monitored via in situ electrochemical atomic force microscopycitations
- 2017Electronic structure design for nanoporous, electrically conductive zeolitic imidazolate frameworks
- 2017Electronic structure design for nanoporous, electrically conductive zeolitic imidazolate frameworkscitations
- 2017Electronic structure design for nanoporous, electrically conductive zeolitic imidazolate frameworkscitations
- 2017Hydrogen Evolution at Liquid|Liquid Interfaces Catalysed by 2D Materialscitations
- 2017Hydrogen evolution and capacitance behavior of Au/Pd nanoparticle-decorated graphene heterostructurescitations
- 2016Metal-organic framework templated electrodeposition of functional gold nanostructurescitations
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article
Anodic dissolution growth of metal-organic framework HKUST-1 monitored via in situ electrochemical atomic force microscopy
Abstract
<p>In situ electrochemical atomic force microscopy (ec-AFM) is utilised for the first time to probe the initial stages of metal-organic framework (MOF) coating growth via anodic dissolution. Using the example of the Cu MOF HKUST-1, real time surface analysis is obtained that supports and verifies many of the reaction steps in a previously proposed mechanism for this type of coating growth. No evidence is observed however for the presence or formation of Cu<sub>2</sub>O, which has previously been suggested to be both key for the formation of the coating and a potential explanation for the anomalously high adhesion strength of coatings obtained via this methodology. Supporting in situ electrochemical Raman spectroscopy also fails to detect the presence of any significant amount of Cu<sub>2</sub>O before or during the coating's growth process.</p>