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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Tuinier, Remco
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Freezing-mediated formation of supraproteins using depletion forcescitations
- 2024Theoretically predicting the solubility of polydisperse polymers using Flory-Huggins theorycitations
- 2023Computational design of anisotropic nanocomposite actuatorscitations
- 2022Effects of polymer nonideality on depletion-induced phase behaviour of colloidal disks and rodscitations
- 2022Distribution of block copolymers in drying polymer filmscitations
- 2021From a eutectic mixture to a deep eutectic system via anion selection:Glutaric acid + tetraethylammonium halidescitations
- 2020Design of Nonideal Eutectic Mixtures Based on Correlations with Molecular Propertiescitations
- 2020Oil-in-water emulsions based on hydrophobic eutectic systemscitations
- 2018Quantification of the liquid window of deep eutectic solventscitations
- 2018Quantification of the liquid window of deep eutectic solventscitations
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article
Quantification of the liquid window of deep eutectic solvents
Abstract
Deep eutectic solvents (DESs) have been considered as a new class of green solvents with tunable physical properties based on the selective combination of their individual components. As the liquid window of a DES identifies the range of feasible applications, it is essential to determine, quantify, and predict their phase behavior. Phase diagrams were measured for systems consisting of tetrapentylammonium bromide and erythritol or succinic acid. Regular solution theory is applied to quantitatively describe the liquid window of DESs. The succinic acid mixture shows a larger deviation from ideal behavior, caused by the stronger hydrogen bond forming acid groups. The interaction parameter between the two DES components in regular solution theory could be determined directly from the eutectic temperature of the mixture and this enables quantification of the degree of non-ideality of DESs.