| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Desmet, Gert
Vrije Universiteit Brussel
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Detailed analysis of the effective and intra-particle diffusion coefficient of proteins at elevated pressure in columns packed with wide-pore core-shell particlescitations
- 2023Development of a 3D-Printable, Porous, and Chemically Active Material Filled with Silica Particles and its Application to the Fabrication of a Microextraction Devicecitations
- 2022Measurement of the molecular diffusion coefficient and the effective longitudinal diffusion under supercritical fluid chromatography conditions in packed bed columnscitations
- 2022Review of recent insights in the measurement and modelling of the B-term dispersion and related mass transfer properties in liquid chromatographycitations
- 2022Vacuum-driven assembly of electrostatically levitated microspheres on perforated surfacescitations
- 2021Measurement and modelling of the intra-particle diffusion and b-term in reversed-phase liquid chromatographycitations
- 2020Spatial Segregation of Microspheres by Rubbing-Induced Triboelectrification on Patterned Surfacescitations
- 2020A Methodology for the Estimation and Modelling of the Obstruction Factor in the Expression for Mesopore Diffusion in Reversed-Phase Liquid Chromatography Particlescitations
- 2019Study of peak capacities generated by a porous layered radially elongated pillar array column coupled to a nano-LC systemcitations
- 2011High-resolution separations of protein isoforms with liquid chromatography time-of-flight mass spectrometry using polymer monolithic capillary columns
- 2011Ultra-high-resolution separations of intact proteins with LC-TOF-MS using polymer monolithic columns
- 2008Errors involved in the Existing B-term Expressions for the Longitudinal Diffusion in Fully Porous Chromatographic Media. Part II: Experimental data in Packed Columns and Surface Diffusion Measurements
Places of action
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article
Study of peak capacities generated by a porous layered radially elongated pillar array column coupled to a nano-LC system
Abstract
<p>The performance of a porous-layered radially elongated pillar (PLREP) array column in a commercial nano-LC system was examined by performing separation of alkylphenones and peptides. The mesoporous silica layer was prepared by sol-gel processing of a mixture of tetramethoxysilane and methyltrimethoxysilane on REPs filling a 16.5 cm long, 1 mm wide channel (three lanes of 5.5 cm long channels connected by turns). The minimum plate height of 1.4 μm for octanophenone (k = 2.21) observed in isocratic mode is 5 times smaller than the smallest off-column plate height previously reported for porous pillar array columns for a retained component. This advantage is related to the earlier introduced shape of the radially elongated pillar bed that outperforms the cylindrically shaped pillar bed in terms of the plate height. In gradient mode, maximum conditional peak capacities of 220 (for a mixture of thiourea and 7 alkylphenones, t<sub>G</sub>= 180 min) and 160 (for a cytochrome c digest, t<sub>G</sub>= 150 min) were obtained. These results indicate excellent potential for implementation of this sol-gel layer in pillar array column formats.</p>