Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (28/28 displayed)

  • 2024Performance polyamides built on a sustainable carbohydrate core23citations
  • 2024Mechanical Properties and Recyclability of Fibre Reinforced Polyester Composites4citations
  • 2023Degradable and Reprocessable Resins from a Dioxolanone Cross-Linker10citations
  • 2023Understanding poly(ethylene terephthalate) degradation using gas-mediated simulated recycling9citations
  • 2020Mechanical Recycling of Packaging Plastics: A Review1074citations
  • 2018Polymeric hole-transport materials with side-chain redox-active groups for perovskite solar cells with good reproducibility4citations
  • 2018Polymeric hole-transport materials with side-chain redox-active groups for perovskite solar cells with good reproducibility4citations
  • 2018Thermal, optical and structural properties of blocks and blends of PLA and P2HEB10citations
  • 2018Functionalizable Stereocontrolled Cyclopolyethers by Ring-Closing Metathesis as Natural Polymer Mimics13citations
  • 2018Morphology of Poly(styrene-co-butadiene) Random Copolymer Thin Films and Nanostructures on a Graphite Surface6citations
  • 2017Thermal, structural and degradation properties of an aromatic-aliphatic polyester built through ring-opening polymerisation82citations
  • 2017Poly(styrene-co-butadiene) Random Copolymer Thin Films and Nanostructures on a Mica Surface: Morphology and Contact Angles of Nanodroplets11citations
  • 2017Olefin cross metathesis and ring-closing metathesis in polymer chemistry66citations
  • 2016Installing Multiple Functional Groups on Biodegradable Polyesters via Post-Polymerization Olefin Cross-Metathesis28citations
  • 2015Aluminum Salen and Salan Polymerization Catalysts19citations
  • 2014Tuning ligand electronics and peripheral substitution on cobalt salen complexes:Structure and polymerisation activity72citations
  • 2014Tuning ligand electronics and peripheral substitution on cobalt salen complexes72citations
  • 2013Aluminium salophen and salen initiators in the ring-opening polymerisation of rac-lactide and rac-β-butyrolactone::Electronic effects on stereoselectivity and polymerisation rates29citations
  • 2013Poly(lactic acid) polymer stars built from early generation dendritic polyols4citations
  • 2013Tacticity-induced changes in the micellization and degradation properties of poly(lactic acid)-block-poly(ethylene glycol) copolymers37citations
  • 2013Aluminium salophen and salen initiators in the ring-opening polymerisation of rac-lactide and rac-β-butyrolactone:29citations
  • 2012Control of thermal properties and hydrolytic degradation in poly(lactic acid) polymer stars through control of isospecificity of polymer arms23citations
  • 2012Anilido-aldimine aluminum complexes:19citations
  • 2012Controlled radical polymerization mediated by Amine-Bis(phenolate) Iron(III) complexes60citations
  • 2012Anilido-aldimine aluminum complexes::Synthesis, characterization and lactide polymerization19citations
  • 2010Tacticity control in the synthesis of poly(lactic acid) polymer stars with dipentaerythritol cores56citations
  • 20084.4,5,5-tetraphenyl-1,3,2-dioxaborolane23citations
  • 2000Trans alkenylpyridine and alkenylamine complexes of platinumcitations

Places of action

Chart of shared publication
Kupper, Yildiz
1 / 1 shared
Puvanenthiran, Kalaiyarasi
1 / 1 shared
Manker, Lorenz P.
1 / 4 shared
Kortsen, Kristoffer
1 / 5 shared
Luterbacher, Jeremy S.
1 / 5 shared
Frauenrath, Holger
1 / 13 shared
Hedou, Maxime A.
1 / 4 shared
Jones, Marie J.
1 / 3 shared
Broggi, Clement
1 / 1 shared
Marti, Roger
1 / 5 shared
Michaud, Véronique
1 / 279 shared
Marechal, Francois
1 / 3 shared
Billington, Eloise
1 / 1 shared
Șucu, Theona
2 / 2 shared
Wang, Meng
1 / 7 shared
Patel, Arpan D.
1 / 1 shared
Pineda, Rosinda Fuentes
1 / 3 shared
Watson, Trystan
2 / 5 shared
Chepelin, Oleg
2 / 3 shared
Robertson, Neil
2 / 15 shared
Sanchez-Molina, Irene
2 / 2 shared
Lake, Benjamin R. M.
2 / 2 shared
Troughton, Joel
2 / 3 shared
Haque, Saif
2 / 3 shared
Fuentes Pineda, Rosinda
1 / 1 shared
Vilas, Jose Luis
2 / 6 shared
Larranaga, Aitor
1 / 3 shared
Makwana, Vishalkumar
1 / 1 shared
Lizundia, Erlantz
2 / 22 shared
Prunet, Joelle
1 / 1 shared
Alkattan, Mohammed
2 / 2 shared
Mcclements, Jake
2 / 4 shared
Koutsos, Vasileios
2 / 7 shared
Sefiane, Khellil
2 / 4 shared
Larrañaga, Aitor
1 / 7 shared
Makwana, Vishalkumar A.
1 / 1 shared
Buffone, Cosimo
1 / 1 shared
Sinclair, Fern
2 / 2 shared
Prunet, Joëlle
1 / 1 shared
Chen, Long
1 / 1 shared
Greenland, Barnaby W.
1 / 11 shared
Macdonald, J. P.
1 / 1 shared
Alcantara, Juan
2 / 2 shared
Storr, Tim
2 / 2 shared
Wang, Michael C. P.
2 / 2 shared
Chiang, Linus
2 / 2 shared
Allan, Laura E. N.
5 / 5 shared
Decken, Andreas
4 / 6 shared
Arnold, Amy E.
2 / 2 shared
Agatemor, Christian
3 / 4 shared
Cross, Edward D.
2 / 2 shared
Grindley, T. Bruce
1 / 1 shared
Keefe, Genny E.
1 / 1 shared
Twibanire, Jean-Damour K.
1 / 1 shared
Cameron, Donald J. A.
4 / 4 shared
Belanger, Justin A.
2 / 2 shared
Callaghan, Laura M.
2 / 2 shared
Reckling, Amy M.
1 / 1 shared
Kozak, Christopher M.
1 / 1 shared
Macdonald, Jarret P.
1 / 1 shared
Bell, Andrew
1 / 7 shared
Wernitz, Sm
1 / 1 shared
Fritschi, Cb
1 / 1 shared
Westcott, Sa
1 / 1 shared
Decken, A.
1 / 1 shared
Vogels, Cm
1 / 1 shared
Westcott, Stephen A.
1 / 2 shared
Biradha, Kumar
1 / 1 shared
Vogels, Christopher M.
1 / 2 shared
Hennigar, Tracy L.
1 / 1 shared
Zaworotko, Michael J.
1 / 3 shared
Wallbank, Andrew I.
1 / 1 shared
Chart of publication period
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2023
2020
2018
2017
2016
2015
2014
2013
2012
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2000

Co-Authors (by relevance)

  • Kupper, Yildiz
  • Puvanenthiran, Kalaiyarasi
  • Manker, Lorenz P.
  • Kortsen, Kristoffer
  • Luterbacher, Jeremy S.
  • Frauenrath, Holger
  • Hedou, Maxime A.
  • Jones, Marie J.
  • Broggi, Clement
  • Marti, Roger
  • Michaud, Véronique
  • Marechal, Francois
  • Billington, Eloise
  • Șucu, Theona
  • Wang, Meng
  • Patel, Arpan D.
  • Pineda, Rosinda Fuentes
  • Watson, Trystan
  • Chepelin, Oleg
  • Robertson, Neil
  • Sanchez-Molina, Irene
  • Lake, Benjamin R. M.
  • Troughton, Joel
  • Haque, Saif
  • Fuentes Pineda, Rosinda
  • Vilas, Jose Luis
  • Larranaga, Aitor
  • Makwana, Vishalkumar
  • Lizundia, Erlantz
  • Prunet, Joelle
  • Alkattan, Mohammed
  • Mcclements, Jake
  • Koutsos, Vasileios
  • Sefiane, Khellil
  • Larrañaga, Aitor
  • Makwana, Vishalkumar A.
  • Buffone, Cosimo
  • Sinclair, Fern
  • Prunet, Joëlle
  • Chen, Long
  • Greenland, Barnaby W.
  • Macdonald, J. P.
  • Alcantara, Juan
  • Storr, Tim
  • Wang, Michael C. P.
  • Chiang, Linus
  • Allan, Laura E. N.
  • Decken, Andreas
  • Arnold, Amy E.
  • Agatemor, Christian
  • Cross, Edward D.
  • Grindley, T. Bruce
  • Keefe, Genny E.
  • Twibanire, Jean-Damour K.
  • Cameron, Donald J. A.
  • Belanger, Justin A.
  • Callaghan, Laura M.
  • Reckling, Amy M.
  • Kozak, Christopher M.
  • Macdonald, Jarret P.
  • Bell, Andrew
  • Wernitz, Sm
  • Fritschi, Cb
  • Westcott, Sa
  • Decken, A.
  • Vogels, Cm
  • Westcott, Stephen A.
  • Biradha, Kumar
  • Vogels, Christopher M.
  • Hennigar, Tracy L.
  • Zaworotko, Michael J.
  • Wallbank, Andrew I.
OrganizationsLocationPeople

article

Poly(styrene-co-butadiene) Random Copolymer Thin Films and Nanostructures on a Mica Surface: Morphology and Contact Angles of Nanodroplets

  • Mcclements, Jake
  • Shaver, Michael P.
  • Buffone, Cosimo
  • Koutsos, Vasileios
  • Sefiane, Khellil
Abstract

The self-assembly of poly(styrene-co-butadiene) random copolymers on mica surfaces was studied by varying solution concentrations and polymer molecular weights. Toluene solutions of the poly(styrene-co-butadiene) samples were spin coated onto a mica surface and the resulting polymer morphology was investigated by atomic force microscopy. At higher concentrations, thin films formed with varying thicknesses; some dewetting was observed which depended on molecular weight. Total dewetting did not occur despite the polymer’s low glass transition temperature. Instead, partial dewetting was observed suggesting the polymer was in a metastable equilibrium state. At lower concentrations, spherical cap shaped nanodroplets formed with varying sizes from single polymer chains to aggregates containing millions of chains. As molecular weight was increased, fewer aggregates were observed on the surface, albeit with larger sizes resulting from increased solution viscosities and more chain entanglements at higher molecular weights. The contact angles of the nanodroplets were shown to be size dependent. A minimum contact angle occurs for droplets with radii of 100 nm – 250 nm at each molecular weight. Droplets smaller than 100 nm showed a sharp increase in contact angle; attributed to an increase in elastic modulus of the droplets, in addition, to a positive line tension value. Droplets larger than 250 nm also showed an increased contact angle due to surface heterogeneities which cannot be avoided for larger droplets. This increase in contact angle plateaus as the droplet size reaches the macroscopic scale.

Topics
  • surface
  • thin film
  • atomic force microscopy
  • glass
  • glass
  • glass transition temperature
  • random
  • molecular weight
  • copolymer
  • self-assembly
  • random copolymer