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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Tissot, Isabel
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2022Analytical Study of Overlooked Bronze Age and Iron Age Goldwork from Northwest Portugalcitations
- 2022New insight into Bronze Age goldwork from northern Portugal. Bracelets, spirals and torcs from the region of Vila Realcitations
- 2019When gold stops glittering: corrosion mechanisms of René Lalique's Art Nouveau jewellerycitations
- 2018Unveiling the art of René Lalique with XRF and Raman spectroscopy – Technological innovation in jewellery productioncitations
- 2017The influence of the constituent elements on the corrosion mechanisms of silver alloys in sulphide environmentscitations
- 2017The influence of the constituent elements on the corrosion mechanisms of silver alloys in sulphide environments: the case of sterling silvercitations
- 2016Corrosion of silver alloys in sulphide environmentscitations
- 2015A multi-analytical approach to gold in Ancient Egypt: Studies on provenance and corrosioncitations
- 2014The effects of the tarnish and corrosion on the conservation assessment of gold alloy objects
- 2013The earrings of Pancas treasure: Analytical study by X-ray based techniques-A first approachcitations
Places of action
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article
The influence of the constituent elements on the corrosion mechanisms of silver alloys in sulphide environments
Abstract
<p>The corrosion of copper and silver in sulphide environments was assessed by several analytical techniques to investigate the influence of each one on the corrosion of sterling silver. The surface colour changes with the immersion time due to the formation of corrosion products composed of particles with distinct sizes and shapes and the consequent layer thickening. Ag<sub>2</sub>S is the main corrosion product of silver. At early stages of corrosion, Cu develops Cu<sub>2</sub>O and Cu<sub>2</sub>S, and later Cu<sub>2</sub>O again. After the corrosion of sterling silver, pure Cu and Ag are compared, and the predominant influence of Cu at the first stages may be suggested whilst Ag mainly contributes to longer corrosion stages. The layer-by-layer corrosion structure observed for the sulphidation of sterling silver was not observed for its constituent elements.</p>