693.932 PEOPLE
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Kočí, Jan | Prague |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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North, Michael
University of York
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (5/5 displayed)
- 2023Biomass Derived, Hierarchically Porous, Activated Starbons® as Adsorbents for Volatile Organic Compoundscitations
- 2021A new acrylated monomer from macaw vegetable oil that polymerizes without external photoinitiatorscitations
- 2017Wholly biomass derivable sustainable polymers by ring-opening metathesis polymerisation of monomers obtained from furfuryl alcohol and itaconic anhydridecitations
- 2016Ring opening metathesis polymerisation of a new bio-derived monomer from itaconic anhydride and furfuryl alcoholcitations
- 2016Ring opening metathesis polymerisation of a new bio-derived monomer from itaconic anhydride and furfuryl alcoholcitations
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article
Wholly biomass derivable sustainable polymers by ring-opening metathesis polymerisation of monomers obtained from furfuryl alcohol and itaconic anhydride
Abstract
Ring-opening metathesis polymerisation (ROMP) of oxanorbornene esters by Grubbs second generation catalyst is used to prepare a range of wholly biomass-derivable homo and copolymers. Eight ester monomers are prepared by esterification of the corresponding carboxylic acid which itself is formed by a 100% atom-economical tandem Diels-Alder-lactonisation reaction ofitaconic anhydride and furfuryl alcohol. The well-controlled nature of the ROMP is confirmed by NMR studies and facilitated the preparation of homopolymers, random copolymers and block copolymers with good control over the polymer molecular weight and molecular weight distribution.