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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Robertson, John
University of Strathclyde
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2022Halide Perovskites: Advanced Photovoltaic Materials Empowered by a Unique Bonding Mechanismcitations
- 2022Printability of pharmaceutical Fused Deposition Modeling (FDM) feedstock material
- 2021Halide Perovskites: Advanced Photovoltaic Materials Empowered by a Unique Bonding Mechanism
- 2019Use of terahertz-Raman spectroscopy to determine solubility of the crystalline active pharmaceutical ingredient in polymeric matrices during hot melt extrusioncitations
- 2018Carbon nanotube isolation layer enhancing in-liquid quality-factors of thin film bulk acoustic wave resonators for gravimetric sensing
- 2018Insulator-to-Metallic Spin-Filtering in 2D-Magnetic Tunnel Junctions Based on Hexagonal Boron Nitridecitations
- 2017Defect passivation of transition metal dichalcogenides via a charge transfer van der Waals interface.
- 2017Low temperature growth of fully covered single-layer graphene using a CoCu catalystcitations
- 2017Low temperature growth of fully covered single-layer graphene using a CoCu catalyst.
- 2016Modelling of co-rotating twin-screw extruders in the pharmaceutical industry I
- 2015High-K materials and metal gates for CMOS applications
- 2015Spatial variability in large area single and few-layer CVD graphene
- 2015Influence of packing density and surface roughness of vertically-aligned carbon nanotubes on adhesive properties of gecko-inspired mimetics.
- 2014Bio-inspired hierarchical polymer fiber-carbon nanotube adhesivescitations
- 2014The role of the sp2:sp3 substrate content in carbon supported nanotube growthcitations
- 2014The role of the sp 2 :sp 3 substrate content in carbon supported nanotube growthcitations
- 2012The phase of iron catalyst nanoparticles during carbon nanotube growthcitations
- 2007Diamond-like carbon for data and beer storagecitations
- 2006Periodic inclusion of room-temperature-ferromagnetic metal phosphide nanoparticles in carbon nanotubescitations
- 2005Materials science: The ultrasmoothness of diamond-like carbon surfacescitations
- 2004Hydrogen content estimation of hydrogenated amorphous carbon by visible Raman spectroscopycitations
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article
Low temperature growth of fully covered single-layer graphene using a CoCu catalyst
Abstract
A bimetallic CoCu alloy thin-film catalyst is developed that enables the growth of uniform, high-quality graphene at 750 °C in 3 min by chemical vapour deposition. The growth outcome is found to vary significantly as the Cu concentration is varied, with ∼1 at% Cu added to Co yielding complete coverage single-layer graphene growth for the conditions used. The suppression of multilayer formation is attributable to Cu decoration of high reactivity sites on the Co surface which otherwise serve as preferential nucleation sites for multilayer graphene. X-ray photoemission spectroscopy shows that Co and Cu form an alloy at high temperatures, which has a drastically lower carbon solubility, as determined by using the calculated Co–Cu–C ternary phase diagram. Raman spectroscopy confirms the high quality (ID/IG < 0.05) and spatial uniformity of the single-layer graphene. The rational design of a bimetallic catalyst highlights the potential of catalyst alloying for producing two-dimensional materials with tailored properties.