Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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Universidade Nova de Lisboa

in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (4/4 displayed)

  • 2018Imine ligands based on ferrocene: Synthesis, structural and Mössbauer characterization and evaluation as chromogenic and electrochemical sensors for Hg2+6citations
  • 2015Reactivity of TCNE and TCNQ derivatives of quinonoid zwitterions with Cu(I)7citations
  • 2014Copper(ii) complexes of bis(aryl-imino)acenaphthene ligands25citations
  • 2012New quinoline α-diimine ligands as fluorescent probes for metal ions: Ultrasound-assisted and conventional synthetic methods7citations

Places of action

Chart of shared publication
Barroso, Sónia
1 / 2 shared
Gaspari, Ana P. S.
1 / 1 shared
Tavares, Pedro
1 / 6 shared
Cordas, Cristina M.
1 / 7 shared
Folgosa, Filipe
1 / 1 shared
Santos-Silva, Teresa
1 / 2 shared
Rosa, V.
4 / 5 shared
Pattacini, Roberto
1 / 1 shared
Sarkar, Biprajit
1 / 8 shared
Kauf, Thomas
1 / 1 shared
Braunstein, Pierre
1 / 3 shared
Deibel, Naina
1 / 1 shared
Gomes, Pedro T.
1 / 5 shared
Lemos, M. Amélia N. D. A.
1 / 1 shared
Gomes, Clara
1 / 8 shared
Aullón, Gabriel
1 / 1 shared
Santos, Carla I. M.
1 / 1 shared
Almeida, Rui M.
1 / 3 shared
Gonzalez, Pablo Javier
1 / 1 shared
Welter, Richard
2 / 2 shared
Pedras, Bruno
1 / 1 shared
Lodeiro, Carlos
1 / 25 shared
Chart of publication period
2018
2015
2014
2012

Co-Authors (by relevance)

  • Barroso, Sónia
  • Gaspari, Ana P. S.
  • Tavares, Pedro
  • Cordas, Cristina M.
  • Folgosa, Filipe
  • Santos-Silva, Teresa
  • Rosa, V.
  • Pattacini, Roberto
  • Sarkar, Biprajit
  • Kauf, Thomas
  • Braunstein, Pierre
  • Deibel, Naina
  • Gomes, Pedro T.
  • Lemos, M. Amélia N. D. A.
  • Gomes, Clara
  • Aullón, Gabriel
  • Santos, Carla I. M.
  • Almeida, Rui M.
  • Gonzalez, Pablo Javier
  • Welter, Richard
  • Pedras, Bruno
  • Lodeiro, Carlos
OrganizationsLocationPeople

article

Imine ligands based on ferrocene: Synthesis, structural and Mössbauer characterization and evaluation as chromogenic and electrochemical sensors for Hg2+

  • Barroso, Sónia
  • Gaspari, Ana P. S.
  • Tavares, Pedro
  • Cordas, Cristina M.
  • Folgosa, Filipe
  • Avilés, Teresa
  • Santos-Silva, Teresa
  • Rosa, V.
Abstract

<p>The compounds 1-naphthyliminoferrocene, 1, and 2-methyl-1-naphthyliminoferrocene, 2, were prepared by the reaction of ferrocenecarboxaldehyde and the corresponding amine, 1-naphthylamine and 2-methyl-1-naphthylamine with one drop of pyrrolidine as the catalyst, in CH<sub>2</sub>Cl<sub>2</sub>, under an inert atmosphere. The compounds were fully characterized by elemental analyses, matrix-assisted laser desorption/ionization-time-of-flight mass spectrometry (MALDI-TOF), FT-IR, <sup>1</sup>H and <sup>13</sup>C NMR as well as two-dimensional, NOESY, COSY and HSQC, NMR spectroscopy. Mössbauer spectroscopic studies were performed to characterize iron species in both compounds. The solid-state molecular structures of compounds 1 and 2 were determined by single crystal X-ray diffraction. Analysis of the electrochemical behaviour of complexes 1 and 2 was performed by cyclic and square wave voltammetry. Compounds 1 and 2 were tested as chromogenic and electrochemical sensors for Hg<sup>2+</sup>.</p>

Topics
  • compound
  • single crystal X-ray diffraction
  • single crystal
  • two-dimensional
  • iron
  • Nuclear Magnetic Resonance spectroscopy
  • amine
  • matrix-assisted laser desorption–ionisation
  • spectrometry
  • molecular structure
  • voltammetry
  • time-of-flight mass spectrometry