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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Avilés, Teresa
Universidade Nova de Lisboa
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2018Imine ligands based on ferrocene: Synthesis, structural and Mössbauer characterization and evaluation as chromogenic and electrochemical sensors for Hg2+citations
- 2015Reactivity of TCNE and TCNQ derivatives of quinonoid zwitterions with Cu(I)citations
- 2014Copper(ii) complexes of bis(aryl-imino)acenaphthene ligandscitations
- 2012New quinoline α-diimine ligands as fluorescent probes for metal ions: Ultrasound-assisted and conventional synthetic methodscitations
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article
Imine ligands based on ferrocene: Synthesis, structural and Mössbauer characterization and evaluation as chromogenic and electrochemical sensors for Hg2+
Abstract
<p>The compounds 1-naphthyliminoferrocene, 1, and 2-methyl-1-naphthyliminoferrocene, 2, were prepared by the reaction of ferrocenecarboxaldehyde and the corresponding amine, 1-naphthylamine and 2-methyl-1-naphthylamine with one drop of pyrrolidine as the catalyst, in CH<sub>2</sub>Cl<sub>2</sub>, under an inert atmosphere. The compounds were fully characterized by elemental analyses, matrix-assisted laser desorption/ionization-time-of-flight mass spectrometry (MALDI-TOF), FT-IR, <sup>1</sup>H and <sup>13</sup>C NMR as well as two-dimensional, NOESY, COSY and HSQC, NMR spectroscopy. Mössbauer spectroscopic studies were performed to characterize iron species in both compounds. The solid-state molecular structures of compounds 1 and 2 were determined by single crystal X-ray diffraction. Analysis of the electrochemical behaviour of complexes 1 and 2 was performed by cyclic and square wave voltammetry. Compounds 1 and 2 were tested as chromogenic and electrochemical sensors for Hg<sup>2+</sup>.</p>