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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sajjad, Muhammad Tariq
London South Bank University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024Improvements in dielectric, electrical and magnetic contributions in Ca0.5Co0.5CrxFe2-xO4 spinel ferrites by the substitution of Cr3+ ions
- 2021Development of Quantum Dot (QD) Based Color Converters for Multicolor Display.
- 2021Development of Quantum Dots (QD) based color converters for multicolor displaycitations
- 2020Direct Growth of Vertically Aligned Carbon Nanotubes onto Transparent Conductive Oxide Glass for Enhanced Charge Extraction in Perovskite Solar Cellscitations
- 2019Triptycene as a supramolecular additive in PTB7:PCBM blends and its influence on photovoltaic propertiescitations
- 2019CuSCN nanowires as electrodes for p-type quantum dot sensitized solar cells : charge transfer dynamics and alumina passivationcitations
- 2019Efficient indoor pin hybrid perovskite solar cells using low temperature solution processed NiO as hole extraction layerscitations
- 2019Interface limited hole extraction from methylammonium lead iodide filmscitations
- 2019Interface limited hole extraction from methylammonium lead iodide filmscitations
- 2019Highly efficient fullerene and non-fullerene based ternary organic solar cells incorporating a new tetrathiocin-cored semiconductorcitations
- 2018Triptycene as a supramolecular additive in PTB7:PCBM blends and its influence on photovoltaic propertiescitations
- 2018Triptycene as a Supramolecular Additive in PTB7: PCBM blends and its Influence on Photovoltaic Propertiescitations
- 2018Improved efficiency of PbS quantum dot sensitized NiO photocathodes with naphthalene diimide electron acceptor bound to the surface of the nanocrystalscitations
- 2018CuSCN nanowires as electrodes for p-type quantum dot sensitized solar cells:charge transfer dynamics and alumina passivationcitations
- 2017Narrow-band anisotropic electronic structure of ReS2citations
- 2017Tuning crystalline ordering by annealing and additives to study its effect on exciton diffusion in a polyalkylthiophene copolymercitations
- 2015Controlling exciton diffusion and fullerene distribution in photovoltaic blends by side chain modificationcitations
- 2015In situ formation and photo patterning of emissive quantum dots in organic small moleculescitations
Places of action
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article
Tuning crystalline ordering by annealing and additives to study its effect on exciton diffusion in a polyalkylthiophene copolymer
Abstract
The influence of various processing conditions on the singlet exciton diffusion is explored in films of a conjugated random copolymer poly-(3-hexylthiophene-co-3-dodecylthiophene) (P3HT-co-P3DDT) and correlated with the degree of crystallinity probed by grazing incidence X-ray scattering and with exciton bandwidth determined from absorption spectra. The exciton diffusion coefficient is deduced from exciton-exciton annihilation measurements and is found to increase by more than a factor of three when thin films are annealed using CS<sub>2</sub> solvent vapour. A doubling of exciton diffusion coefficient is observed upon melt annealing at 200 °C and the corresponding films show about 50% enhancement in the degree of crystallinity. In contrast, films fabricated from polymer solutions containing a small amount of either solvent additive or nucleating agent show a decrease in exciton diffusion coefficient possibly due to formation of traps for excitons. Our results suggest that the enhancement of exciton diffusivity occurs because of increased crystallinity of alkyl-stacking and longer conjugation of aggregated chains which reduces the exciton bandwidth.