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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Salvador, M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2021Toward Stable Monolithic Perovskite/Silicon Tandem Photovoltaics: A Six-Month Outdoor Performance Study in a Hot and Humid Climatecitations
- 2016Morphological and electrical control of fullerene dimerization determines organic photovoltaic stabilitycitations
- 2016Organic and perovskite solar modules innovated by adhesive top electrode and depth-resolved laser patterningcitations
- 2016Combined Computational Approach Based on Density Functional Theory and Artificial Neural Networks for Predicting the Solubility Parameters of Fullerenescitations
- 2016Increased thermal stabilization of polymer photovoltaic cells with oligomeric PCBMcitations
- 2015Water ingress in encapsulated inverted organic solar cells: Correlating infrared imaging and photovoltaic performancecitations
- 2015Air-processed organic tandem solar cells on glass: Toward competitive operating lifetimescitations
- 2015An Alternative Strategy to Adjust the Recombination Mechanism of Organic Photovoltaics by Implementing Ternary Compoundscitations
- 2015Low-Temperature Solution-Processed Kesterite Solar Cell Based on in Situ Deposition of Ultrathin Absorber Layercitations
- 2015Pushing efficiency limits for semitransparent perovskite solar cellscitations
- 2015Photophysics of Molecular-Weight-Induced Losses in Indacenodithienothiophene-Based Solar Cellscitations
- 2014Flexible organic tandem solar modules with 6% efficiency: combining roll-to-roll compatible processing with high geometric fill factorscitations
- 2014Flexible organic tandem solar modules: A story of up-scaling
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article
Increased thermal stabilization of polymer photovoltaic cells with oligomeric PCBM
Abstract
International audience ; The first oligomerisation of phenyl-C61-butyric acid methyl ester (PCBM) using a facile atom transfer radical addition polymerization (ATRAP) and its exploitation for organic photovoltaic devices is described. Oligo\(phenyl-C61-butyric acid methyl ester)-alt-[1,4-bis(bromomethyl)-2,5-bis(octyloxy)benzene]\ (OPCBMMB) shows opto-electronic properties equivalent to those of PCBM but has a higher glass transition temperature. When mixed with various band gap semiconducting polymers, OPCBMMB delivers performances similar to PCBM but with an enhanced stabilization of the bulk heterojunction in photovoltaic devices on plastic substrates under thermal stress, regardless of the degree of crystallinity of the polymer and without changing opto-electronic properties. © 2016 The Royal Society of Chemistry.