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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Brousse, Thierry
Nantes Université
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (35/35 displayed)
- 2024Enhanced Li<sup>+</sup> and Mg<sup>2+</sup> Diffusion at the Polymer–Ionic Liquid Interface within PVDF‐Based Ionogel Electrolytes for Batteries and Metal‐Ion Capacitorscitations
- 2024Nanofeather ruthenium nitride electrodes for electrochemical capacitorscitations
- 2024Enhanced Li + and Mg 2+ Diffusion at the Polymer–Ionic Liquid Interface within PVDF‐Based Ionogel Electrolytes for Batteries and Metal‐Ion Capacitorscitations
- 2024Tuning Deposition Conditions for VN Thin Films Electrodes for Microsupercapacitors: Influence of the Thicknesscitations
- 2024Control of microstructure and composition of reactively sputtered vanadium nitride thin films based on hysteresis curves and application to microsupercapacitorscitations
- 2023Major Improvement in the Cycling Ability of Pseudocapacitive Vanadium Nitride Films for Micro‐Supercapacitorcitations
- 2023Structure and Electrochemical Properties of Bronze Phase Materials Containing Two Transition Metalscitations
- 2022Sputtered (Fe,Mn)<sub>3</sub>O<sub>4</sub> Spinel Oxide Thin Films for Micro-Supercapacitorcitations
- 2022Ag2V4O11: from primary to secondary batterycitations
- 2022Sputtered (Fe,Mn) 3 O 4 Spinel Oxide Thin Films for Micro-Supercapacitorcitations
- 2022Three-Dimensional TiO2 Film Deposited by ALD on Porous Metallic Scaffold for 3D Li-Ion Micro-Batteries: A Road towards Ultra-High Capacity Electrodecitations
- 2022Three-Dimensional TiO2 Film Deposited by ALD on Porous Metallic Scaffold for 3D Li-Ion Micro-Batteries: A Road towards Ultra-High Capacity Electrodecitations
- 2021Sodium borohydride (NaBH 4 ) as a high-capacity material for next-generation sodium-ion capacitorscitations
- 2021Influence of ion implantation on the charge storage mechanism of vanadium nitride pseudocapacitive thin filmscitations
- 2018Prototyping Aqueous Electrochemical Capacitors
- 2018Stabilizing the Structure of LiCoPO4 Nanocrystals via Addition of Fe3+: Formation of Fe3+ Surface Layer, Creation of Diffusion-Enhancing Vacancies, and Enabling High-Voltage Battery Operationcitations
- 2018On chip interdigitated micro-supercapacitors based on sputtered bifunctional vanadium nitride thin films with finely tuned inter- and intracolumnar porositiescitations
- 2018Stabilizing the Structure of LiCoPO4 Nanocrystals via Addition of Fe3+: Formation of Fe3+ Surface Layer, Creation of Diffusion-Enhancing Vacancies, and Enabling High-Voltage Battery Operation ; Stabilizing the Structure of LiCoPO4 Nanocrystals via Addition of Fe3+: Formation of Fe3+ Surface Layer, Creation of Diffusion-Enhancing Vacancies, and Enabling High-Voltage Battery Operation: Formation of Fe 3+ Surface Layer, Creation of Diffusion-Enhancing Vacancies, and Enabling High-Voltage Battery Operationcitations
- 2017Improved electro-grafting of nitropyrene onto onion-like carbon via in situ electrochemical reduction and polymerization: tailoring redox energy density of the supercapacitor positive electrodecitations
- 2017Improved electro-grafting of nitropyrene onto onion-like carbon via in situ electrochemical reduction and polymerization: tailoring redox energy density of the supercapacitor positive electrodecitations
- 2017High areal energy 3D-interdigitated micro-supercapacitors in aqueous and ionic liquid electrolytescitations
- 2017Tuning the Cation Ordering with the Deposition Pressure in Sputtered LiMn1.5Ni0.5O4 Thin Film Deposited on Functional Current Collectors for Li-Ion Microbattery Applicationscitations
- 2016Ultrafast charge–discharge characteristics of a nanosized core–shell structured LiFePO4 material for hybrid supercapacitor applicationscitations
- 2016Atomic Layer Deposition of Functional Layers for on Chip 3D Li-Ion All Solid State Microbatterycitations
- 2015Chemical modification of graphene oxide through diazonium chemistry and its influence on the structure-properties relationships of graphene oxide-iron oxide nanocompositescitations
- 2015Chemical Modification of Graphene Oxide through Diazonium Chemistry and Its Influence on the Structure-Property Relationships of Graphene Oxide-Iron Oxide Nanocompositescitations
- 2015Electrochemical Performance of Carbon/MnO2 Nanocomposites Prepared via Molecular Bridging as Supercapacitor Electrode Materialscitations
- 2014Step-conformal deposition of TiO2 and MnO2 electrodes on advanced silicon microstructures for 3D Li-ion microbatteries and micro-supercapacitors
- 2013Impact of the morphological characteristics on the supercapacitive electrochemical performances of FeOx/Reduced Graphene Oxide nanocompositescitations
- 2013Nanosilicon-based thick negative composite electrodes for lithium batteries with graphene as conductive additivecitations
- 2013Nanosilicon-Based Thick Negative Composite Electrodes for Lithium Batteries with Graphene as Conductive Additivecitations
- 2013Nanosilicon‐Based Thick Negative Composite Electrodes for Lithium Batteries with Graphene as Conductive Additivecitations
- 2012In situ redox functionalization of composite electrodes for high power-high energy electrochemical storage systems via a non-covalent approachcitations
- 2012New strategies for preparing nanocomposites as electrode materials for Li-ion batteries and electrochemical capacitors
- 2007Silicon/graphite nanocomposite electrodes prepared by low pressure chemical vapor depositioncitations
Places of action
Organizations | Location | People |
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article
Improved electro-grafting of nitropyrene onto onion-like carbon via in situ electrochemical reduction and polymerization: tailoring redox energy density of the supercapacitor positive electrode
Abstract
Herein, we report a improved method for the physical grafting of 1-nitropyrene (Pyr-NO2) onto highly graphitized carbon onion. This is achieved through a lowering of the onset potential of the pyrene polymerization via in situ reduction of the NO2 group. The additional redox activity pertaining to the reduced NO2 enables exceeding the faradaic capacity which is associated with the p-doping of the grafted pyrene backbone, as observed for pyrene, 1-aminopyrene, and unreduced Pyr-NO2. Theoretical calculations demonstrate the charge transfer and binding enthalpy capabilities of Pyr-NO2, which are significantly higher than those of the other two species, and which allow for improved p-stacking on the carbon surface. Upon 20 wt % grafting of Pyr-NO2, the capacity of the electrode jumps from 20 mAh g-1 electrode to 38 mAh g-1 electrode, which corresponds to 110 mAh g-1 per mass of Pyr-NO2 and the average potential is increased by 200 mV. Very interestingly, this high performance is also coupled with outstanding retention with respect to both the initial capacity for more than 4000 cycles, as well as the power characteristics, demonstrating the considerable advantages of employing the present in situ grafting technique.