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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Christensen, Dennis Valbjørn
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2023Perspectives on oxide heterostructures – the curious case of γ-Al 2 O 3 /SrTiO 3citations
- 2023Reconstruction of Low Dimensional Electronic States by Altering the Chemical Arrangement at the SrTiO3 Surfacecitations
- 2023Perspectives on oxide heterostructures – the curious case of γ-Al2O3/SrTiO3citations
- 2022On the thermoelectric properties of Nb-doped SrTiO 3 epitaxial thin filmscitations
- 2022Freestanding Perovskite Oxide Filmscitations
- 2019Electrical, magnetic and magnetotransport properties of Na and Mo doped Ca3Co4O9 materialscitations
- 2019Electrical, magnetic and magnetotransport properties of Na and Mo doped Ca 3 Co 4 O 9 materialscitations
- 2019Diluted Oxide Interfaces with Tunable Ground Statescitations
- 2018Exploring magnetic and electronic properties in γ-Al2O3/SrTiO3
- 2018Exploring magnetic and electronic properties in γ-Al 2 O 3 /SrTiO 3
- 2018High-temperature thermoelectric properties of Na- and W-Doped Ca3Co4O9 system citations
- 2017Microscopic origin of the mobility enhancement at a spinel/perovskite oxide heterointerface revealed by photoemission spectroscopycitations
- 2016Scandium-doped zinc cadmium oxide as a new stable n-type oxide thermoelectric materialcitations
- 2012On the origin of metallic conductivity at the interface of LaAlO3/SrTiO3citations
- 2012Resistance switching of the interfacial conductance in amorphous SrTiO3 heterostructures
Places of action
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article
Scandium-doped zinc cadmium oxide as a new stable n-type oxide thermoelectric material
Abstract
Scandium-doped zinc cadmium oxide (Sc-doped ZnCdO) is proposed as a new n-type oxide thermoelectric material. The material is sintered in air to maintain the oxygen stoichiometry and avoid instability issues. The successful alloying of CdO with ZnO at a molar ratio of 1 : 9 significantly reduced the thermal conductivity by up to 7-fold at room temperature. By carefully selecting the Sc-dopant concentrations, a high power factor of 7.1 × 10<sup>−4</sup> W m<sup>−1</sup> K<sup>−2</sup> at 1173 K could be obtained. Therefore, the highest ZT ∼ 0.3 at 1173 K was achieved for the Zn<sub>0.9</sub>Cd<sub>0.1</sub>Sc<sub>0.01</sub>O<sub>1.015</sub> sample, and it has so far one of the highest ZT values among those reported for ZnO based thermoelectric materials over the temperature range, e.g., its ZT value at 300 K, which is 0.012, is over 1 order of magnitude higher than that of the state-of-the-art nanostructured Al-doped ZnO, which is 0.0013. It suggests that this material is a good candidate for improving the overall conversion efficiencies in oxide thermoelectric modules. Meanwhile, Sc-doped ZnCdO is robust in air at high temperatures, whereas other n-type materials, such as Al-doped ZnO, will experience rapid degradation of their electrical conductivity and ZT.