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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Le, Thanh Hung
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2019Contact of ZnSb thermoelectric material to metallic electrodes using S-Bond 400 solder alloycitations
- 2017Efficient p-n junction-based thermoelectric generator that can operate at extreme temperature conditionscitations
- 2017Microstructure and chemical data of the thermoelectric ZnSb material after joining to metallic electrodes and heat treatmentcitations
- 2016On the Challenges of Reducing Contact Resistances in Thermoelectric Generators Based on Half-Heusler Alloyscitations
- 2016On the Challenges of Reducing Contact Resistances in Thermoelectric Generators Based on Half-Heusler Alloyscitations
- 2016Effects of spark plasma sintering conditions on the anisotropic thermoelectric properties of bismuth antimony telluridecitations
- 2016Scandium-doped zinc cadmium oxide as a new stable n-type oxide thermoelectric materialcitations
- 2013The Influence of α- and γ-Al 2 O 3 Phases on the Thermoelectric Properties of Al-doped ZnOcitations
- 2013The Influence of α- and γ-Al2O3 Phases on the Thermoelectric Properties of Al-doped ZnOcitations
- 2012High-temperature segmented thermoelectric oxide module using p-type Ca3Co4O9 and n-type ZnAlO/CaMn0.95Nb0.05O3 legs
- 2012High-temperature segmented thermoelectric oxide module using p -type Ca 3 Co 4 O 9 and n -type ZnAlO/CaMn 0.95 Nb 0.05 O 3 legs
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article
Scandium-doped zinc cadmium oxide as a new stable n-type oxide thermoelectric material
Abstract
Scandium-doped zinc cadmium oxide (Sc-doped ZnCdO) is proposed as a new n-type oxide thermoelectric material. The material is sintered in air to maintain the oxygen stoichiometry and avoid instability issues. The successful alloying of CdO with ZnO at a molar ratio of 1 : 9 significantly reduced the thermal conductivity by up to 7-fold at room temperature. By carefully selecting the Sc-dopant concentrations, a high power factor of 7.1 × 10<sup>−4</sup> W m<sup>−1</sup> K<sup>−2</sup> at 1173 K could be obtained. Therefore, the highest ZT ∼ 0.3 at 1173 K was achieved for the Zn<sub>0.9</sub>Cd<sub>0.1</sub>Sc<sub>0.01</sub>O<sub>1.015</sub> sample, and it has so far one of the highest ZT values among those reported for ZnO based thermoelectric materials over the temperature range, e.g., its ZT value at 300 K, which is 0.012, is over 1 order of magnitude higher than that of the state-of-the-art nanostructured Al-doped ZnO, which is 0.0013. It suggests that this material is a good candidate for improving the overall conversion efficiencies in oxide thermoelectric modules. Meanwhile, Sc-doped ZnCdO is robust in air at high temperatures, whereas other n-type materials, such as Al-doped ZnO, will experience rapid degradation of their electrical conductivity and ZT.