| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Vos, Dirk De
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2022Choline chloride–ethylene glycol based deep-eutectic solvents as lixiviants for cobalt recovery from lithium-ion battery cathode materials: are these solvents really green in high-temperature processes?citations
- 2021Porosimetry for Thin Films of Metal–Organic Frameworkscitations
- 2020Solvent-Free Powder Synthesis and Thin Film Chemical Vapor Deposition of a Zinc Bipyridyl-Triazolate Frameworkcitations
- 2017Gel-based morphological design of zirconium metal-organic frameworkscitations
- 2015Catalytic and Physicochemical Polymer Processing in Ionic Liquids
- 2014Value-added products through electrochemical CO2 fixation and decarboxylation
- 2013Dehydrochlorination of poly(vinyl chloride) and chlorinated polyethylene by phosphonium ionic liquids
- 2013High pressure, high temperature synthesis of metal-organic frameworks
- 2013Electrochemical dicarboxylation of conjugated fatty acids as an efficient valorization of carbon dioxidecitations
- 2012Electrochemical fixation of carbon dioxide in conjugated dienes: synthesis of valuable carboxylic acids
- 2011Cellulose Valorization in Ionic Liquids
- 2010Redoxreacties in ionische vloeistoffen gekoppeld aan productafscheiding
- 2009Optimization of the ionic liquid composition for the palladium-catalyzed hydrogenolysis of aromatic ketones
- 2008Catalytic reductions in ionic liquids
- 2008Catalytic Hydrogenolysis of Aromatic Ketones in Mixed Choline–Betainium Ionic Liquidscitations
Places of action
| Organizations | Location | People |
|---|
article
Gel-based morphological design of zirconium metal-organic frameworks
Abstract
<p>The ability of metal-organic frameworks (MOFs) to gelate under specific synthetic conditions opens up new opportunities in the preparation and shaping of hierarchically porous MOF monoliths, which could be directly implemented for catalytic and adsorptive applications. In this work, we present the first examples of xero-or aerogel monoliths consisting solely of nanoparticles of several prototypical Zr<sup>4+</sup>-based MOFs: UiO-66-X (X = H, NH<sub>2</sub>, NO<sub>2</sub>, (OH)<sub>2</sub>), UiO-67, MOF-801, MOF-808 and NU-1000. High reactant and water concentrations during synthesis were observed to induce the formation of gels, which were converted to monolithic materials by drying in air or supercritical CO<sub>2</sub>. Electron microscopy, combined with N<sub>2</sub> physisorption experiments, was used to show that irregular nanoparticle packing leads to pure MOF monoliths with hierarchical pore systems, featuring both intraparticle micropores and interparticle mesopores. Finally, UiO-66 gels were shaped into monolithic spheres of 600 μm diameter using an oil-drop method, creating promising candidates for packed-bed catalytic or adsorptive applications, where hierarchical pore systems can greatly mitigate mass transfer limitations.</p>