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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vincze, Laszlo
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2022Hybrid lanthanide-doped rattle-type thermometers for theranosticscitations
- 2022The influence of bases on thermal decomposition synthesis of LaF3
- 2020An X-ray ray tracing simulation code for mono- and polycapillaries : description, advances and applicationcitations
- 2020Highly sensitive nondestructive rare earth element detection by means of wavelength-dispersive X-ray fluorescence spectroscopy enabled by an energy dispersive pn-charge-coupled-device detectorcitations
- 2017Sensing the framework state and guest molecules in MIL-53(Al) via the electron paramagnetic resonance spectrum of V-IV dopant ionscitations
- 2016Confocal depth-resolved micro-X-ray absorption spectroscopy study of chemically strengthened boroaluminosilicate glassescitations
- 2016Enhanced gas sorption and breathing properties of the new sulfone functionalized COMOC-2 metal organic frameworkcitations
- 2009Characterization of non-aged and aged modern Prussian Blue pigments by Mössbauer spectroscopy, x-ray powder diffraction and x-ray absorption spectroscopy
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article
Confocal depth-resolved micro-X-ray absorption spectroscopy study of chemically strengthened boroaluminosilicate glasses
Abstract
It is crucial to understand the structural origins of macroscopic properties in silicate glasses for their high-tech applications. An example of such an application is chemically strengthened boroaluminosilicate glasses that are exposed to an ion exchange process during which alkali ions (e.g. Na+) are replaced by larger (e.g. K+) ions. Despite the empirically thorough understanding of this exchange process, much less is known about the fundamental physics of the process. Since Fe atoms are a suitable probe for monitoring chemical stress-induced changes in the local structure in the chemically strengthened glasses, a set of chemically strengthened boroaluminosilicate glasses containing 1 mol% Fe2O3 are here studied using depth-resolved confocal X-ray absorption near-edge structure (XANES) and extended Xray absorption fine structure (EXAFS) spectroscopy. Information on the Fe oxidation state, coordination number, and bond distance as a function of the sample depth and glass composition is obtained. These new insights on chemical stress-induced changes will aid in the further development and improvement of such damage-resistant glasses.