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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Borrega, Marc
VTT Technical Research Centre of Finland
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2023Evaluation of chemical additives in hydrothermal pre-treatment of wood for the integrated production of monosugars and hydrolysis lignins for PLA-based biocompositescitations
- 2022Utilizing and Valorizing Oat and Barley Straw as an Alternative Source of Lignocellulosic Fiberscitations
- 2022Utilizing and Valorizing Oat and Barley Straw as an Alternative Source of Lignocellulosic Fiberscitations
- 2022Valorization of Industrial Spruce Bark by Alkaline Extraction
- 2020Morphological and Wettability Properties of Thin Coating Films Produced from Technical Ligninscitations
- 2016Wood biorefinery based on γ-valerolactone/water fractionationcitations
- 2015Composition and structure of balsa (Ochroma pyramidale) woodcitations
- 2015Mechanics of balsa (Ochroma pyramidale) woodcitations
- 2011Radial mechanical properties of high-temperature dried Norway spruce (Picea abies) woodcitations
- 2011Cell wall porosity in norway spruce wood as affected by high-temperature drying
- 2010Three mechanisms affecting the mechanical properties of spruce wood dried at high temperaturescitations
- 2008Effect of relative humidity on thermal degradation of Norway spruce (Picea abies) woodcitations
Places of action
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article
Wood biorefinery based on γ-valerolactone/water fractionation
Abstract
A novel biorefinery concept based on the fractionation of woody biomass in a γ-valerolactone (GVL)/water binary mixture is introduced. Under optimal GVL/water ratio, Eucalyptus globulus wood was effectively fractionated in a single step into its principal components. The pulp fraction, characterized by high yield, high cellulose purity and high bleachability, was directly spun to produce regenerated cellulosic fibers with mechanical properties comparable to the best man-made fibers currently available in the market. Most of the hemicelluloses and lignin in wood were extracted and dissolved into the spent liquor. The dissolved hemicellulose-based fraction may be upgraded to furanic platform chemicals in subsequent catalytic conversion processes. About 50-60% of the extracted lignin was precipitated by the addition of water, an anti-solvent. The precipitated lignin was characterized by low carbohydrate and ash contamination, high phenolic content, relatively low polydispersity and low molecular mass. The lignin extracted by GVL/water fractionation may thus be suitable for a wide range of energy, material or chemical applications.