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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Wolska-Pietkiewicz, Małgorzata
Warsaw University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2024High‐Performance Perovskite Solar Cells with Zwitterion‐Capped‐ZnO Quantum Dots as Electron Transport Layer and <scp>NH<sub>4</sub></scp>X (X = F, Cl, Br) Assisted Interfacial Engineeringcitations
- 2021From Uncommon Ethylzinc Complexes Supported by Ureate Ligands to Water-Soluble ZnO Nanocrystals: A Mechanochemical Approachcitations
- 2021ZnO Nanoplatelets with Controlled Thickness: Atomic Insight into Facet‐Specific Bimodal Ligand Binding Using DNP NMRcitations
- 2016Alkylzinc diorganophosphates: synthesis, structural diversity and unique ability to incorporate zincoxane unitscitations
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article
Alkylzinc diorganophosphates: synthesis, structural diversity and unique ability to incorporate zincoxane units
Abstract
Equimolar reactions between ZntBu2 and diphenyl phosphate (dpphe-H) or dimethyl phosphate (dmphe-H) result in the formation of [tBuZn(O2P(OR′)2)]-type compounds which crystallize as tetranuclear aggregates, [tBuZn(dpphe)]4 (14) or [tBuZn(dmphe)]4 (24), with the phosphate ligands spanning 4-coordinate Zn centers. The utility of ZnMe2 instead of ZntBu2 dramatically changes the reaction outcome and leads to [MeZn(O2P(OR′)2)]-type moieties incorporating zincoxane units, i.e., pentanuclear [{MeZn(dpphe)}3(Me2Zn2O)(THF)2] (3) and nonanuclear [{MeZn(dmphe)}6(Me2Zn3O2)] (4) aggregates. The resulting compounds were characterized by 1H and 31P NMR spectroscopy and single-crystal X-ray diffraction analysis.