| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Lowe, John P.
University of Bath
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2021Multi-nuclear, high-pressure, operando FlowNMR spectroscopic study of Rh/PPh3 – catalysed hydroformylation of 1-hexene
- 2019Triphasic Nature of Polymers of Intrinsic Microporosity Induces Storage and Catalysis Effects in Hydrogen and Oxygen Reactivity at Electrode Surfacescitations
- 2016Aminopiperidine based complexes for lactide polymerisationcitations
- 2016Aerosol-assisted CVD of SnO from stannous alkoxide precursorscitations
- 2014Preparation of stereoregular isotactic poly(mandelic acid) through organocatalytic ring-opening polymerization of a cyclic O-carboxyanhydridecitations
- 2008Fundamental studies of gas sorption within mesopores situated amidst an inter-connected, irregular networkcitations
Places of action
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article
Aerosol-assisted CVD of SnO from stannous alkoxide precursors
Abstract
<p>The stannous alkoxides [Sn(OR)<sub>2</sub>] [R = i-Pr, t-Bu, C(Et)Me<sub>2</sub>, CHPh<sub>2</sub>, CPh<sub>3</sub>] have been synthesised by reaction of Sn(NR′<sub>2</sub>)<sub>2</sub> with two equivalents of HOR [R′ = Me, R = i-Pr; R′ = SiMe<sub>3</sub>, R = t-Bu, C(Et)Me<sub>2</sub>, CHPh<sub>2</sub>, CPh<sub>3</sub>]. Single crystal X-ray diffraction analysis of the bis(diphenylmethoxide) (4) and bis(triphenylmethoxide) (5) species have shown them to comprise three-coordinate Sn(ii) centres through dimerisation in the solid state with the alkoxide units adopting transoid and cisoid configurations across the {Sn<sub>2</sub>O<sub>2</sub>} cores respectively. Thermogravimetric analysis indicates clean decomposition and some evidence of volatility at temperatures >200 °C for all three aliphatic alkoxides, whereas both the diphenyl- and triphenylmethoxide compounds provide higher decomposition temperatures and, for the triphenylmethoxide derivative, a residual mass consistent with the formation of a carbon-containing residue. The previously reported iso-propoxide (1) and tert-butoxide (2) derivatives have been utilised in toluene solution to deposit SnO thin films by aerosol-assisted chemical vapour deposition (AACVD) on glass at temperatures between 300 and 450 °C. While SnO is deposited under hot wall conditions as the only identifiable phase by p-XRD and Raman spectroscopy for both precursors, morphological analysis by SEM reveals inferior substrate coverage in comparison to previously reported ureide-based precursor systems.</p>