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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Zachara, Janusz
Warsaw University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2018Thermally induced structural transformations of linear coordination polymers based on aluminum tris(diorganophosphates)citations
- 2016Linear Coordination Polymers Based on Aluminum Phosphates: Synthesis, Crystal Structure and Morphologycitations
- 2015Compressed Arsenolite As4O6 and Its Helium Clathrate As4O6·2Hecitations
- 2015Cascade of High-Pressure Transitions of Claudetite II and the First Polar Phase of Arsenic(III) Oxidecitations
- 2015Role of Lewis bases in reactions of aluminum and gallium trialkyls with 2-mercaptobenzoxazolecitations
- 2013An insight into coordination ability of dicyanoimidazolato anions toward lithium in presence of acetonitrile. Crystal structures of novel lithium battery electrolyte saltscitations
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article
Linear Coordination Polymers Based on Aluminum Phosphates: Synthesis, Crystal Structure and Morphology
Abstract
Several aluminum tris(diorganophosphates) have been synthesized and characterized via elemental analysis, NMR, FT-IR and Raman spectroscopy, as well as powder XRD, and SEM. Single-crystal X-ray diffraction studies revealed that the aluminum tris(diethylphosphate) crystal structure comprises two crystallographically nonequivalent catena-Al[O2P(OEt)2]3 chains propagating along the c-axis. Their parallel orientation favors the formation of closely packed hexagonal domains. PXRD data suggest that other homologues have a similar structure, with the interchain distance closely corresponding to the dimensions of organic ligands. They are also susceptible to a reversible dissociation to ionic species under the effect of primary amines. This feature can be utilized for the synthesis of epoxy nanocomposites.