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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Norrman, Kion
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (40/40 displayed)
- 2019Diluted Oxide Interfaces with Tunable Ground Statescitations
- 2018Oxygen Exchange and Transport in (La0.6Sr0.4)0.98FeO3-d – Ce0.9Gd0.1O1.95 Dual-Phase Compositescitations
- 2018High-temperature thermoelectric properties of Na- and W-Doped Ca3Co4O9 system citations
- 2018Oxygen Exchange and Transport in (La 0.6 Sr 0.4 ) 0.98 FeO 3-d – Ce 0.9 Gd 0.1 O 1.95 Dual-Phase Compositescitations
- 2017Mid-IR optical properties of silicon doped InPcitations
- 2017Dynamic and Impure Perovskite Structured Metal Oxide Surfacescitations
- 2016New Hypothesis for SOFC Ceramic Oxygen Electrode Mechanismscitations
- 2016In situ X-ray scattering of perovskite solar cell active layers roll-to-roll coated on flexible substratescitations
- 2016In situ X-ray scattering of perovskite solar cell active layers roll-to-roll coated on flexible substratescitations
- 2015Polarization Induced Changes in LSM Thin Film Electrode Composition Observed by In Operando Raman Spectroscopy and TOF-SIMS
- 2015Dynamic behavior of impurities and native components in model LSM microelectrodes on YSZcitations
- 2014TOF-SIMS characterization of impurity enrichment and redistribution in solid oxide electrolysis cells during operationcitations
- 2014TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices – the ISOS-3 inter-laboratory collaborationcitations
- 2013Oxygen Electrode Kinetics and Surface Composition of Dense (La0.75Sr0.25)0.95MnO3 on YSZcitations
- 2013All polymer photovoltaics: From small inverted devices to large roll-to-roll coated and printed solar cellscitations
- 2013All polymer photovoltaics: From small inverted devices to large roll-to-roll coated and printed solar cellscitations
- 2013Oxygen Electrode Kinetics and Surface Composition of Dense (La 0.75 Sr 0.25 ) 0.95 MnO 3 on YSZcitations
- 2012TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices - the ISOS-3 inter-laboratory collaborationcitations
- 2012TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices - the ISOS-3 inter-laboratory collaborationcitations
- 2012Stability of Polymer Solar Cellscitations
- 2012Comprehensive Investigation of Silver Nanoparticle/Aluminum Electrodes for Copper Indium Sulfide/Polymer Hybrid Solar Cellscitations
- 2012TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices–the ISOS-3 inter-laboratory collaborationcitations
- 2012Rapid flash annealing of thermally reactive copolymers in a roll-to-roll process for polymer solar cellscitations
- 2012TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices – the ISOS-3 inter-laboratory collaborationcitations
- 2012TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices – the ISOS-3 inter-laboratory collaborationcitations
- 2012Simultaneous multilayer formation of the polymer solar cell stack using roll-to-roll double slot-die coating from watercitations
- 2012Simultaneous multilayer formation of the polymer solar cell stack using roll-to-roll double slot-die coating from watercitations
- 2011Aqueous Processing of Low-Band-Gap Polymer Solar Cells Using Roll-to-Roll Methodscitations
- 2011Aqueous Processing of Low-Band-Gap Polymer Solar Cells Using Roll-to-Roll Methodscitations
- 2011Oxygen- and water-induced degradation of an inverted polymer solar cell: the barrier effectcitations
- 2011Water and oxygen induced degradation of small molecule organic solar cellscitations
- 2010Using Light-Induced Thermocleavage in a Roll-to-Roll Process for Polymer Solar Cellscitations
- 2010Degradation Patterns in Water and Oxygen of an Inverted Polymer Solar Cellcitations
- 2010Degradation Patterns in Water and Oxygen of an Inverted Polymer Solar Cellcitations
- 2010Stability and Degradation of Polymer Solar cells
- 2009Water-Induced Degradation of Polymer Solar Cells Studied by (H2O)-O-18 Labelingcitations
- 2008Effects of trace elements at the Ni/ScYSZ interface in a model solid oxide fuel cell anodecitations
- 2007Analysis of the failure mechanism for a stable organic photovoltaic during 10 000 h of testingcitations
- 2006Lifetimes of organic photovoltaics: Design and synthesis of single oligomer molecules in order to study chemical degradation mechanismscitations
- 2006Oxygen release and exchange in niobium oxide MEHPPV hybrid solar cellscitations
Places of action
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article
In situ X-ray scattering of perovskite solar cell active layers roll-to-roll coated on flexible substrates
Abstract
In an effort to understand recent results showing differences between the power conversion efficiencies of lead halide (CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub>-<sub>x</sub>Cl<sub>x</sub>) solar cells on glass versus flexible substrates, this study investigates the influence that substrate and processing methods have on morphological and crystallographic development. Using our in situ slot-die micro roll-to-roll coater setup, we measured small and wide angle X-ray scattering in grazing incidence while the material dried, enabling us to follow the crystallization from just after the deposition and up to 25 minutes later. The data showed differing crystallographic developments between the substrates, especially seen through the behaviour of a crystalline precursor which survived longer on the flexible substrates than on glass. Additionally, the common degradation product PbI<sub>2</sub> was absent on the thickest flexible substrate. This leads us to conjecture that the flexible substrates absorb part of the solvent, thereby delaying evaporation and changing the solvent environment around the perovskite. As a further test, we produced solar cells with the same substrates and confirmed that the ones made on flexible substrates performed worse than those made on glass, but that when including an ITO layer in the stack it seemed to act as a buffer, whereby the solar cell performance was improved.