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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Trofod, Thue
Danish Technological Institute
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2016In situ X-ray scattering of perovskite solar cell active layers roll-to-roll coated on flexible substratescitations
- 2015Matrix Organization and Merit Factor Evaluation as a Method to Address the Challenge of Finding a Polymer Material for Roll Coated Polymer Solar Cellscitations
- 2015Upscaling of Perovskite Solar Cells: Fully Ambient Roll Processing of Flexible Perovskite Solar Cells with Printed Back Electrodescitations
- 2014All-Solution-Processed, Ambient Method for ITO-Free, Roll-Coated Tandem Polymer Solar Cells using Solution- Processed Metal Filmscitations
- 2013Roll-to-Roll Inkjet Printing and Photonic Sintering of Electrodes for ITO Free Polymer Solar Cell Modules and Facile Product Integrationcitations
- 2013All polymer photovoltaics: From small inverted devices to large roll-to-roll coated and printed solar cellscitations
- 2012Silver front electrode grids for ITO-free all printed polymer solar cells with embedded and raised topographies, prepared by thermal imprint, flexographic and inkjet roll-to-roll processescitations
- 2012Simultaneous multilayer formation of the polymer solar cell stack using roll-to-roll double slot-die coating from watercitations
- 2011Aqueous Processing of Low-Band-Gap Polymer Solar Cells Using Roll-to-Roll Methodscitations
- 2011Generation of native polythiophene/PCBM composite nanoparticles via the combination of ultrasonic micronization of droplets and thermocleaving from aqueous dispersioncitations
Places of action
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article
In situ X-ray scattering of perovskite solar cell active layers roll-to-roll coated on flexible substrates
Abstract
In an effort to understand recent results showing differences between the power conversion efficiencies of lead halide (CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub>-<sub>x</sub>Cl<sub>x</sub>) solar cells on glass versus flexible substrates, this study investigates the influence that substrate and processing methods have on morphological and crystallographic development. Using our in situ slot-die micro roll-to-roll coater setup, we measured small and wide angle X-ray scattering in grazing incidence while the material dried, enabling us to follow the crystallization from just after the deposition and up to 25 minutes later. The data showed differing crystallographic developments between the substrates, especially seen through the behaviour of a crystalline precursor which survived longer on the flexible substrates than on glass. Additionally, the common degradation product PbI<sub>2</sub> was absent on the thickest flexible substrate. This leads us to conjecture that the flexible substrates absorb part of the solvent, thereby delaying evaporation and changing the solvent environment around the perovskite. As a further test, we produced solar cells with the same substrates and confirmed that the ones made on flexible substrates performed worse than those made on glass, but that when including an ITO layer in the stack it seemed to act as a buffer, whereby the solar cell performance was improved.