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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Suzuki, Kiyonori
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2023Effect of grain size on the core loss of nanocrystalline Fe86B13Cu1 prepared by ultra-rapid annealingcitations
- 2022Resolving the Complex Spin Structure in Fe-Based Soft Magnetic Nanocrystalline Material by Magnetic Small-Angle Neutron Scattering
- 2022Unraveling the magnetic softness in Fe–Ni–B-based nanocrystalline material by magnetic small-angle neutron scatteringcitations
- 2022Uniaxial polarization analysis of bulk ferromagnets: theory and first experimental resultscitations
- 2020Magnetic Guinier lawcitations
- 2020Engineered Porous Nanocomposites That Deliver Remarkably Low Carbon Capture Energy Costscitations
- 2017Fe3O4@HKUST-1 and Pd/Fe3O4@HKUST-1 as magnetically recyclable catalysts prepared via conversion from a Cu-based ceramiccitations
- 2017Copper-free nanocrystalline soft magnetic materials with high saturation magnetization comparable to that of Si steelcitations
- 2015Lead(II) uptake by aluminium based magnetic framework composites (MFCs) in watercitations
- 2013Magnetization reversal in Nd-Fe-B based nanocomposites as seen by magnetic small-angle neutron scatteringcitations
- 2012The use of plasma treatment for simultaneous carbonization and reduction of iron oxide/polypyrrole core/shell nanoparticlescitations
- 2012Phase reduction of coated maghemite (γ-Fe2O3) nanoparticles under microwave-induced plasma heating for rapid heat treatmentcitations
- 2011Ferromagnetism of polythiophene-capped Au nanoparticles
- 2011Synthesis and electromagnetic interference shielding properties of iron oxide/polypyrrole nanocompositescitations
- 2010Functional magnetic nanocomposites for EMI shielding
- 2009Potential blends of magnetic nano-composites for EMI shielding applications
Places of action
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article
Lead(II) uptake by aluminium based magnetic framework composites (MFCs) in water
Abstract
<p>The recent combination of Metal-Organic Frameworks (MOFs) and magnetic nanoparticles has shown their potential as a composite material in practical applications including drug delivery, catalysis and pollutant sequestration. Here, we report for the first time the preparation of a robust magnetic nanocomposite material based on an aluminium MOF (MIL-53) and iron oxide nanoparticles for the uptake of lead(ii) ions. Different aminofunctionalized MIL-53 MOFs were prepared by increasing the 2-aminoterephthalic/terephthalic acid ratio. The composite materials were tested to determine the sequestration capability of heavy metals from various solvents (methanol, DMSO and water), pH (2, 7, 12) and a range of Pb(ii) concentrations (10-8000 ppm). The magnetic composite based on MIL-53 showed remarkable capacity to sequester Pb(ii) ions from water (up to 492.4 mg g<sup>-1</sup> of composite), the highest recorded for a MOF sorbent system to date. While the MOF played a crucial role in the efficient heavy metal uptake, the magnetic nanoparticles allowed the prompt collection of the sorbent from solution. The triggered release of Pb(ii) was investigated using an alternating magnetic field. The exceptional adsorption capacity and the response to the magnetic field make this class of innovative functional material a promising candidate for environmental remediation technologies.</p>