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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Thydén, Karl Tor Sune
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2018Deposition of highly oriented (K,Na)NbO3 films on flexible metal substratescitations
- 2016Effects of strong cathodic polarization of the Ni-YSZ interfacecitations
- 2016Comparison of ultramicrotomy and focused-ion-beam for the preparation of TEM and STEM cross section of organic solar cellscitations
- 2016Conductivity and structure of sub-micrometric SrTiO 3 -YSZ compositescitations
- 2016Conductivity and structure of sub-micrometric SrTiO3-YSZ compositescitations
- 2015Plasma properties during magnetron sputtering of lithium phosphorous oxynitride thin filmscitations
- 2015Fast mass interdiffusion in ceria/alumina compositecitations
- 2015Investigation of Novel Electrocatalysts for Metal Supported Solid Oxide Fuel Cells - Ru:GDCcitations
- 2014In situ surface reduction of a NiO-YSZ-alumina composite using scanning probe microscopycitations
- 2013Oxidation in ceria infiltrated metal supported SOFCs – A TEM investigationcitations
- 2013Oxidation in ceria infiltrated metal supported SOFCs – A TEM investigationcitations
- 2013Transmission Electron Microscopy Specimen Preparation Method for Multiphase Porous Functional Ceramicscitations
- 2013Transmission Electron Microscopy Specimen Preparation Method for Multiphase Porous Functional Ceramicscitations
- 2013Infiltrated SrTiO3:FeCr‐based Anodes for Metal‐Supported SOFCcitations
- 2013Infiltrated SrTiO 3 :FeCr‐based Anodes for Metal‐Supported SOFCcitations
- 2012Durable and Robust Solid Oxide Fuel Cells
- 2012Characterization of impregnated GDC nano structures and their functionality in LSM based cathodescitations
- 2011Modifications of interface chemistry of LSM–YSZ composite by ceria nanoparticlescitations
- 2008Microstructural degradation of Ni-YSZ anodes for solid oxide fuel cells
- 2006Degradation of conductivity and microstructure under thermal and current load in Ni-YSZ cermets for SOFC anodescitations
Places of action
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article
Fast mass interdiffusion in ceria/alumina composite
Abstract
Gadolinium-doped ceria (CGO) presents unique processes at low oxygen partial pressure (pO2 < 1012 atm) and low temperatures (T > 800 C) such as faster mass diffusion, which are not observed in conventional sintering under ambient air conditions. In CGO/Al2O3 composites the resulting effects driven by such mass diffusion are low viscosity flows and high reactivity between phases, indicated by the formation of CeAlO3. This reaction is promoted by the high content of oxygen defects and the chemical reduction of Ce4+ cations to Ce3+ in CGO/Al2O3 composites under low temperature and low pO2. In this work, a comparison is made between sintering CGO/Al2O3 under ambient air conditions and under low pO2, focusing on densification, viscosity and the evolution of the microstructure.