| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Whittaker, Michael
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2016The pharmacokinetics and biodistribution of a 64 kDa PolyPEG star polymer after subcutaneous and pulmonary administration to ratscitations
- 2015Rapid synthesis of ultrahigh molecular weight and low polydispersity polystyrene diblock copolymers by RAFT-mediated emulsion polymerizationcitations
- 2015Delivering nitric oxide with nanoparticlescitations
- 2015Molecular weight (hydrodynamic volume) dictates the systemic pharmacokinetics and tumour disposition of PolyPEG star polymerscitations
- 2014Nano-sized graphene oxide as sole surfactant in miniemulsion polymerization for nanocomposite synthesiscitations
- 2014Photoinduced sequence-control via one pot living radical polymerization of acrylatescitations
- 2012Modification of graphene/graphene oxide with polymer brushes using controlled/living radical polymerizationcitations
- 2011High-order multiblock copolymers via iterative Cu(0)-mediated radical polymerizations (SET-LRP): Toward biological precisioncitations
- 2010Synthesis of hollow polymer nanocapsules exploiting gold nanoparticles as sacrificial templatescitations
- 2009Self-assembly of well-defined amphiphilic polymeric miktoarm stars, dendrons, and dendrimers in water: The effect of architecturecitations
- 2008Synthesis of linear and 4-arm star block copolymers of poly (methyl acrylate-b-solketal aerylate) by SET-LRP at 25 Ccitations
- 2008Convergent synthesis of second generation AB-type miktoarm dendrimers using "click" chemistry catalyzed by copper wirecitations
- 2008Self-assembly of amphiphilic polymeric dendrimers synthesized with selective degradable linkagescitations
- 2007Reactive alkyne and azide solid supports to increase purity of novel polymeric stars and dendrimers via the "click" reactioncitations
- 2006Synthesis of 3-miktoarm stars and 1st generation mikto dendritic copolymers by "living" radical polymerization and "click" chemistrycitations
Places of action
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article
Rapid synthesis of ultrahigh molecular weight and low polydispersity polystyrene diblock copolymers by RAFT-mediated emulsion polymerization
Abstract
Reversible-deactivation radical polymerization techniques can be used to produce large and complex macromolecules for a wide range of applications. However, RAFT and related techniques are not readily applicable to the synthesis of well-defined, ultrahigh molecular weight polymers from monomers that have a low propagation rate coefficient (such as styrene). Herein we report the use of a novel water-soluble macro-stabilizer in the RAFT-mediated emulsion polymerization of styrene yielding an ultrafast synthesis of ultrahigh molecular weight, low polydispersity polystyrene diblock copolymers to very high conversion. This environmentally friendly emulsion technique produces uniform nanoparticles with precise control over molecular weight and particle size, presenting great potential for many applications.