People | Locations | Statistics |
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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Terryn, Herman
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (124/124 displayed)
- 2024On the Interaction between PEDOT:PSS Dispersions and Aluminium Electrodes for Solid State Electrolytic Capacitorscitations
- 2024Application of operando ORP-EIS for the in-situ monitoring of acid anion incorporation during anodizingcitations
- 2024Effect of Impregnation of PEDOT:PSS in Etched Aluminium Electrodes on the Performance of Solid State Electrolytic Capacitors
- 2024Surface engineering of aerospace aluminium alloyscitations
- 2023Operando odd random phase electrochemical impedance spectroscopy (ORP-EIS) for in-situ monitoring of the Zr-based conversion coating growth in the presence of (in)organic additivescitations
- 2023Differentiating between the diffusion of water and ions from aqueous electrolytes in organic coatings using an integrated spectro-electrochemical techniquecitations
- 2023Identification of carbon‐containing phases in electrodeposited hard Fe–C coatings with intentionally codeposited carbon
- 2023Electrophoretic Deposition (EPD): An Alternative To Obtain Better Polymer Aluminium Electrolytic Capacitors
- 2023Identification of carbon-containing phases in electrodeposited hard Fe–C coatings with intentionally codeposited carbon
- 2023Pre-eruptive storage conditions and magmatic evolution of the Bora-Baricha-Tullu Moye volcanic system, Main Ethiopian Riftcitations
- 2023Surface modification of biodegradable Mg alloy by adapting µEDM capabilities with cryogenically-treated tool electrodescitations
- 2023Investigation of hybrid Zr-aminosilane treatment formation on zinc substrate and comparison to advanced high strength stainless steelcitations
- 2022Unravelling the chemisorption mechanism of epoxy-amine coatings on Zr-based converted galvanized steel by combined static XPS/ToF-SIMS approachcitations
- 2022Growth kinetics and passive behavior of the native oxide film on additively manufactured AlSi10Mg versus the conventional cast alloycitations
- 2022Albumin Protein Adsorption on CoCrMo Implant Alloycitations
- 2022Unraveling the mechanism of the conversion treatment on Advanced High Strength Stainless Steels (AHSSS)citations
- 2022The Role of Cu-Based Intermetallic on the Direct Growth of a ZnAl LDH Film on AA2024citations
- 2022Unraveling the formation mechanism of hybrid Zr conversion coating on advanced high strength stainless steelscitations
- 2022Revisiting the surface characterization of plasma-modified polymerscitations
- 2021Role of phosphate, calcium species and hydrogen peroxide on albumin protein adsorption on surface oxide of Ti6Al4V alloycitations
- 2021Editors' Choice - Dealloying-Driven Cerium Precipitation on Intermetallic Particles in Aerospace Aluminium Alloyscitations
- 2021The mechanism of thermal oxide film formation on low Cr martensitic stainless steel and its behavior in fluoride-based pickling solution in conversion treatmentcitations
- 2021Scrutinizing the importance of surface chemistry versus surface roughness for aluminium/sol-gel film adhesioncitations
- 2021Nanoscopic and in-situ cross-sectional observations of Li-based conversion coating formation using liquid-phase TEMcitations
- 2021Laterally-resolved formation mechanism of a lithium-based conversion layer at the matrix and intermetallic particles in aerospace aluminium alloyscitations
- 2021Effect of Homogenization Temperature and Soaking Time on the Microstructure and Corrosion Properties of a Twin Roll Casted AA3003citations
- 2021On the relationship between the plasma characteristics, the microstructure and the optical properties of reactively sputtered TiO2 thin filmscitations
- 2021Assessment of Carbon-Titanium Multilayer Coatings on Aluminum as Bipolar Plates in PEM Fuel Cellscitations
- 2021Effect of Sr Addition to a Modified AA3003 on Microstructural and Corrosion Propertiescitations
- 2021A combined XPS/ToF-SIMS approach for the 3D compositional characterization of Zr-based conversion of galvanized steelcitations
- 2020Nanorods grown by copper anodizing in sodium carbonatecitations
- 2020Dealloying-driven local corrosion by intermetallic constituent particles and dispersoids in aerospace aluminium alloyscitations
- 2020In-situ nanoscopic observations of dealloying-driven local corrosion from surface initiation to in-depth propagationcitations
- 2020A Review on Anodizing of Aerospace Aluminum Alloys for Corrosion Protectioncitations
- 2020Molecular Characterization of Bonding Interactions at the Buried Steel Oxide-Aminopropyl Triethoxysilane Interface Accessed by Ar Cluster Sputteringcitations
- 202050 shades of colourcitations
- 2020Effect of zirconium-based conversion treatments of zinc, aluminium and magnesium on the chemisorption of ester-functionalized moleculescitations
- 2020Cross-sectional characterization of the conversion layer formed on AA2024-T3 by a lithium-leaching coatingcitations
- 2020ATR-FTIR in Kretschmann configuration integrated with electrochemical cell as in situ interfacial sensitive tool to study corrosion inhibitors for magnesium substrates
- 2020ATR-FTIR in Kretschmann configuration integrated with electrochemical cell as in situ interfacial sensitive tool to study corrosion inhibitors for magnesium substratescitations
- 2020Effect of simulated brazing on the microstructure and corrosion behavior of twin roll cast AA3003citations
- 2020Molecular Characterization of Multiple Bonding Interactions at the Steel Oxide - Aminopropyl triethoxysilane Interface by ToF-SIMScitations
- 2020The effect of time evolution and timing of the electrochemical data recording of corrosion inhibitor protection of hot-dip galvanized steelcitations
- 2020Evaluation of particle and bed integrity of aqueous size-exclusion columns packed with sub-2 µm particles operated at high pressurecitations
- 2020Effect of surface roughness and chemistry on the adhesion and durability of a steel-epoxy adhesive interfacecitations
- 2020The role of hydrogen bond donor and water content on the electrochemical reduction of Ni2+ from solvents - an experimental and modelling studycitations
- 2020A review on adhesively bonded aluminium joints in the automotive industrycitations
- 2019Highly Robust MOF Polymeric Beads with a Controllable Size for Molecular Separationscitations
- 2019Active corrosion protection of various aluminium alloys by lithium-leaching coatingscitations
- 2019A complementary electrochemical approach for time-resolved evaluation of corrosion inhibitor performancecitations
- 2019Study of peak capacities generated by a porous layered radially elongated pillar array column coupled to a nano-LC systemcitations
- 2019Characterisation of rapid water uptake in model coatings using instantaneous impedance
- 2019Dual Role of Lithium on the Structure and Self-Healing Ability of PMMA-Silica Coatings on AA7075 Alloycitations
- 2019Numerical interpretation to differentiate hydrogen trapping effects in iron alloys in the Devanathan-Stachurski permeation cellcitations
- 2019Electrodeposition of Nickel Based Nanostructures from Deep Eutectic Solvent / Water Mixtures As Electrocatalysts for the Oxygen Evolution Reaction
- 2019The chemical throwing power of lithium-based inhibitors from organic coatings on AA2024-T3citations
- 2019Effect of brazing on the microstructure and corrosion behaviour of a twin roll cast Al-Mn-Fe-Si alloy system
- 2019Electrophysical properties of Sr2FeMoO6–δ ceramics with dielectric shellscitations
- 2019Influence of water content and applied potential on the electrodeposition of Ni coatings from deep eutectic solventscitations
- 2019An in situ spectro-electrochemical monitoring of aqueous effects on polymer/metal oxide interfacescitations
- 2019Effect of the shear layer on the etching behavior of 6060 aluminum extrusion alloyscitations
- 2019Molybdate-phosphate conversion coatings to protect steel in a simulated concrete pore solutioncitations
- 2019Effect of Zn on the grain boundary precipitates and resulting alkaline etching of recycled Al-Mg-Si-Cu alloyscitations
- 2018Advanced (In Situ) Surface Analysis of Organic Coating/Metal Oxide Interactions for Corrosion Protection of Passivated Metalscitations
- 2018On the importance of irreversibility of corrosion inhibitors for active coating protection of AA2024-T3citations
- 2018Comparison of Electrochemical and Thermal Evaluation of Hydrogen Uptake in Steel Alloys Having Different Microstructurescitations
- 2018Role of Si in the Anodizing Behavior of Al-Si Alloys: Additive Manufactured and Cast Al-Si10-Mgcitations
- 2018In situ methanol adsorption on aluminum oxide monitored by a combined ORP-EIS and ATR-FTIR Kretschmann setupcitations
- 2018Compositional study of a corrosion protective layer formed by leachable lithium salts in a coating defect on AA2024-T3 aluminium alloyscitations
- 2018Odd Random Phase Electrochemical Impedance Spectroscopy to Study the Corrosion Behavior of Hot Dip Zn and Zn-Alloy Coated Steel Wires in Sodium Chloride Solutioncitations
- 2018The use of odd random phase electrochemical impedance spectroscopy to study lithium-based corrosion inhibition by active protective coatingscitations
- 2018An in-situ XANES investigation of the interactions between iron, manganese and antimony in silicate meltscitations
- 2018Fluoride-Induced Interfacial Adhesion Loss of Nanoporous Anodic Aluminium Oxide Templates in Aerospace Structurescitations
- 2017Interface strength and degradation of adhesively bonded porous aluminum oxidescitations
- 2017Interface strength and degradation of adhesively bonded porous aluminum oxidescitations
- 2017Interface strength and degradation of adhesively bonded porous aluminum oxidescitations
- 2017The influence of a Zr-based conversion treatment on interfacial bonding strength and stability of epoxy coated carbon steelcitations
- 2017Influence of grain size on the electrochemical behavior of pure coppercitations
- 2017Use of local electrochemical methods (SECM, EC-STM) and AFM to differentiate microstructural effects (EBSD) on very pure coppercitations
- 2017Electrochemical evaluation of corrosion inhibiting layers formed in a defect from lithium-leaching organic coatingscitations
- 2017Towards Cr(VI)-free anodization of aluminum alloys for aerospace adhesive bonding applicationscitations
- 2017In Situ Characterization of the Initial Effect of Water on Molecular Interactions at the Interface of Organic/Inorganic Hybrid Systemscitations
- 2017Comprehensive Study of the Electrodeposition of Nickel Nanostructures from Deep Eutectic Solvents: Self-Limiting Growth by Electrolysis of Residual Watercitations
- 2017Fatigue Performance of Ti-6Al-4V Additively Manufactured Specimens with Integrated Capillaries of an Embedded Structural Health Monitoring Systemcitations
- 2017Development of an Electrochemical Procedure for Monitoring Hydrogen Sorption/Desorption in Steelcitations
- 2017Unravelling the chemical influence of water on the PMMA/aluminum oxide hybrid interface in situcitations
- 2017Adhesive bonding and corrosion performance investigated as a function of auminum oide chemistry and adhesivescitations
- 2016Smart corrosion protection by multi-action self-healing polymeric coatingscitations
- 2016Electrodeposition of Nickel Nanoparticles from Choline Chloride - Urea Deep Eutectic Solvent
- 2016Lithium salts as leachable corrosion inhibitors and potential replacement for hexavalent chromium in organic coatings for the protection of aluminum alloyscitations
- 2016A Multiple-Action Self-Healing Coatingcitations
- 2016Fatigue of Ti6Al4V Structural Health Monitoring Systems Produced by Selective Laser Meltingcitations
- 2016Study of the formation of a protective layer in a defect from lithium-leaching organic coatingscitations
- 2016Influence of Applied Potential, Water Content and Forced Convection on the Electrodeposition of Ni Films on Steel from Choline Chloride Based Deep Eutectic Solvents
- 2016An investigation of the corrosion inhibitive layers generated from lithium oxalatecontaining organic coating on AA2024-T3 aluminium alloycitations
- 2016Electrodeposition of Nickel Nanostructures from Deep Eutectic Solvents
- 2016Potentiodynamic anodizing of aluminum alloys in Cr(VI)-free electrolytescitations
- 2016Electrodeposition of Nickel from Deep Eutectic Solvents
- 2015The corrosion protection of AA2024-T3 aluminium alloy by leaching of lithium-containing salts from organic coatingscitations
- 2015The corrosion protection of AA2024-T3 aluminium alloy by leaching of lithium-containing salts from organic coatingscitations
- 2015Monitoring carbon steel behavior under biotic and abiotic conditionscitations
- 2015Protective Film Formation on AA2024-T3 Aluminum Alloy by Leaching of Lithium Carbonate from an Organic Coating
- 2015XPS Analysis of the Surface Chemistry and Interfacial Bonding of Barrier-Type Cr(VI)-Free Anodic Oxidescitations
- 2015Probing the interface between ultrathin polymeric films and Aluminum oxide: in-situ investigation of the electrolyte diffusion throughout the coating
- 2015Non-destructive 3-dimensional mapping of microcapsules in polymeric coatings by confocal Raman spectroscopycitations
- 2015The role of crystal diversity in understanding mass transfer in nanoporous materialscitations
- 2015Iron speciation in soda-lime-silica glass: a comparison of Xanes and UV-vis-NIR spectroscopycitations
- 2015Evaluation of Different Topologies of Integrated Capillaries in Effective Structural Health Monitoring System Produced by 3D Printingcitations
- 2014In situ scanning tunneling microscopy study of the intergranular corrosion of copper
- 20143D Printing for Intelligent Metallic Structures
- 2013A generalized electrochemical aggregative growth mechanism
- 2013Corrosion Study on Al-rich Metal-Coated Steel by Odd >Random Phase Multisine Electrochemical Impedance Spectroscopy
- 2013An infrared spectroscopic study of sodium silicate adsorption on porous anodic alumina
- 2013Mechanism of corrosion protection of hot-dip aluminium-silicon coatings on steel studied by electrochemical depth profilingcitations
- 2013Effect of surface composition and microstructure of aluminised steel on the formation of a titanium-based conversion layer
- 2013Structure and Formation Mechanism of Rolled-in Oxide Areas on Aluminum Lithographic Printing Sheets
- 2013Early stages during localized corrosion of AA2024 TEM specimens in chloride environment
- 2012Combined EBSD and AFM study of the corrosion behaviour of ETP-Cucitations
- 2011Self-healing property characterization of reversible thermoset coatings
- 2011A combined mechanical, microscopic and local electrochemical evaluation of self-healing properties of shape-memory polyurethane coatings (available online)
- 2010Silicate-based post-anodic treatment for lithographic application
- 2009Transversal load sensing with fiber Bragg gratings in microstructured optical fibers
- 2008The influence of pre-treatment of aluminium-magnesium alloy on bonding of organic coatings
- 2007Towards a nano-scale electrochemical and spectroscopic characterization of organic layers on oxide surfaces
Places of action
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article
Iron speciation in soda-lime-silica glass: a comparison of Xanes and UV-vis-NIR spectroscopy
Abstract
Scientific analyses of ancient glasses have been carried out for many years using elemental chemical analysis. However, it is known that the control of the redox conditions in the glass melt has a strong implication on the final hue of glass because it affects Fe2+/SFe. Therefore an increasing number of studies on the redox conditions have been published in recent years by means of synchrotron based Xray absorption spectroscopy. This is a technique which is not easily accessible and requires dedicated facilities. In this paper we describe an alternative approach by means of optical absorption spectroscopy. We synthesised 10 soda-lime-silica glasses with known redox conditions and iron concentration to calibrate the absorption at 1100 nm as a function of Fe2+ concentration. The linear extinction coefficient was also determined. These glasses were also studied by means of X-ray Absorption Near Edge Structure (XANES) spectroscopy. Electron paramagnetic resonance spectroscopy was additionally used as an ancillary method to verify the quality of our data. Furthermore 28 samples from real archaeological samples were analysed by XANES and optical spectroscopy as a case study. The Fe2+/SFe values obtained were compared and demonstrated that the two techniques were in good agreement with each other. Optical spectroscopy can be applied in situ with moderate sample preparation to determine the concentration of Fe2+. To investigate the redox conditions, especially as a first screening approach, this methodology is an important tool to take into consideration before applying more sophisticated techniques such as XANES, which is more elaborate and requires high-tech resources.