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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Pownceby, Mark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2023Experimental phase equilibria and liquidus of CaO-Al2O3-SiO2-Na2O-B2O3 slags relevant to e-waste processing
- 2023Deportment of metals from e-waste PCBs towards alloy and slag phases during smelting using CaO-Al2O3-SiO2-B2O3 slagscitations
- 2022Effect of B2O3 on the Liquidus Temperature and Phase Equilibria in the CaO–Al2O3–SiO2–B2O3 Slag System, Relevant to the Smelting of E-wastecitations
- 2021Phase equilibria study of CaO-Al2O3-SiO2-Na2O slags for smelting waste printed circuit boardscitations
- 2021Characterisation of SFCA phases in iron ore sinter by combined optical microscopy and electron probe microanalysis (EPMA)
- 2021Characterisation of SFCA phases in iron ore sinter by combined optical microscopy and electron probe microanalysis (EPMA)
- 2021Experimental determination of liquidus temperature and phase equilibria of the CaO-Al2O3-SiO2-Na2O slag system relevant to e-waste smeltingcitations
- 2021Beneficiation of low-grade, goethite-rich iron ore using microwave-assisted magnetizing roastingcitations
- 2021Automated Optical Image Analysis of Iron Ore Sintercitations
- 2019Characterisation of phosphorus and other impurities in goethite-rich iron ores – Possible P incorporation mechanismscitations
- 2016Development of a niobium-doped titania inert anode for titanium electrowinning in molten chloride saltscitations
- 2014Effect of sintering conditions on the formation of mineral phases during iron ore sintering with New Zealand ironsand
- 2013In situ X-ray and neutron diffraction studies of silico-ferrite of calcium and aluminium iron ore sinter phase formation
- 2011In situ diffraction studies of phase formation during iron ore sintering
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article
Development of a niobium-doped titania inert anode for titanium electrowinning in molten chloride salts
Abstract
The direct electrochemical reduction of solid titanium dioxide in a chloride melt is an attractive method for the production of titanium metal. It has been estimated that this type of electrolytic approach may reduce the costs of producing titanium sponge by more than half, with the additional benefit of a smaller environmental footprint. The process utilises a consumable carbon anode which releases a mixture of CO2 and CO gas during electrolysis, but suffers from low current efficiency due to the occurrence of parasitic side reactions involving carbon. The replacement of the carbon anode with a cheap, robust inert anode offers numerous benefits that include: elimination of carbon dioxide emissions, more efficient cell operation, opportunity for three-dimensional electrode configurations and reduced electrode costs. This paper reports a study of Nb-doped titania anode materials for inert anodes in a titanium electrolytic reduction cell. The study examines the effect of niobium content and sintering conditions on the performance of Nb-doped TiO2 anodes in laboratory-scale electrolysis tests. Experimental findings, including performance in a 100 h laboratory electrolysis test, are described.