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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Amela-Cortes, Maria
University of Rennes
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2023Flexible and Transparent Luminescent Cellulose-Transition Metal Cluster Compositescitations
- 2023From Solid-State Cluster Compounds to Functional PMMA-Based Composites with UV and NIR Blocking Properties, and Tuned Hues
- 2022Nanoarchitectonics of Glass Coatings for Near-Infrared Shielding: From Solid-State Cluster-Based Niobium Chlorides to the Shaping of Nanocomposite Filmscitations
- 2021Poly(dimethylsiloxane) functionalized with complementary organic and inorganic emitters for the design of white emissive waveguidescitations
- 2021Expanding the Toolbox of Octahedral Molybdenum Clusters and Nanocomposites Made Thereof: Evidence of Two-Photon Absorption Induced NIR Emission and Singlet Oxygen Productioncitations
- 2020Preparation and characterization of hollow silica nanocomposite functionalized with UV absorbable molybdenum clustercitations
- 2020Switchable Two-Dimensional Waveguiding Abilities of Luminescent Hybrid Nanocomposites for Active Solar Concentratorscitations
- 2019Transparent functional nanocomposite films based on octahedral metal clusters synthesis by electrophoretic deposition process and characterizationcitations
- 2018Lord of The Crowns A New Precious in the Kingdom of Clustomesogenscitations
- 2018Direct Integration of Red-NIR Emissive Ceramic-like AnM6Xi8Xa6 Metal Cluster Salts in Organic Copolymers Using Supramolecular Interactionscitations
- 2018Low dimensional solids based on Mo-6 cluster cyanides and Mn2+, Mn3+ or Cd2+ metal ions crystal chemistry, magnetic and optical propertiescitations
- 2016Versatility of the ionic assembling method to design highly luminescent PMMA nanocomposites containing [M6Qi8La6]n- octahedral nano-building blockscitations
- 2016Time-gated luminescence bioimaging with new luminescent nanocolloids based on [Mo6I8(C2F5COO)(6)](2-) metal atom clusterscitations
- 2016Efficient active waveguiding properties of Mo6 nano-cluster-doped polymer nanotubes
- 2016Facile design of red-emitting waveguides using hybrid nanocomposites made of inorganic clusters dispersed in SU8 photoresist hostcitations
- 2015Tuned red NIR phosphorescence of polyurethane hybrid composites embedding metallic nanoclusters for oxygen sensingcitations
- 2014Deep red luminescent hybrid copolymer materials with high transition metal cluster contentcitations
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article
Versatility of the ionic assembling method to design highly luminescent PMMA nanocomposites containing [M6Qi8La6]n- octahedral nano-building blocks
Abstract
New luminescent poly(methylmethacrylate) (PMMA) nanocomposites with high content of different hexanuclear octahedral cluster building blocks, namely [Mo6I8(C2F5COO6)](2-), [Re6Se8(CN)6](4-) and [W6Cl14](2-) have been prepared by free-radical polymerisation. To do so, cluster complexes bearing a polymerisable ammonium counter-cation have been synthesised. In this way, we demonstrate that ionic assembling is a powerful tool to functionalise easily any type of anionic cluster units to be introduced in a PMMA organic matrix. All samples remain homogeneous, stable during several months, and retain the luminescence properties of the cluster precursor.