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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Woollins, John Derek
University of St Andrews
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2021Synthesis and structural characterization of Zn2+, Cd2+ and Hg2+ complexes with tripyrrolidinophosphine chalcogenidescitations
- 2021Synthetic and structural study of peri-substituted phosphine-arsinescitations
- 2019Synthesis, characterization, and structural properties of mercury(II), cadmium(II) and zinc(II) tripiperidinophosphine chalcogenide complexescitations
- 2018Synthesis, spectroscopic, and structural characterization of new functionalized gem-bisphosphonate complexes of tin(IV) chloride
- 2018A study of through-space and through-bond JPP coupling in a rigid nonsymmetrical bis(phosphine) and its metal complexescitations
- 2017Dye-sensitized solar cellscitations
- 2016Varying the flexibility of the aromatic backbone in half sandwich rhodium(III) dithiolato complexescitations
- 2016Synthesis, characterization and structures of cadmium(II) and mercury(II) complexes with bis(dipiperidinylphosphino)methylamine dichalcogenidescitations
- 2015Spirocyclic, macrocyclic and ladder complexes of coinage metals and mercury with dichalcogeno P2N2-supported anionscitations
- 2015Rhodium(III) and iridium(III) half-sandwich complexes with tertiary arsine and stibine ligandscitations
- 2015Peri-substituted phosphorus-tellurium systems – an experimental and theoretical investigation of the P∙∙∙Te through-space interactioncitations
- 2015Synthesis and properties of the heterospin (S1 = S2 = 1/2) radical-ion salt bis(mesitylene)molybdenum(I) [1,2,5]thiadiazolo[3,4-c][1,2,5]thiadiazolidylcitations
- 2012Structure-Property Relationships in PtII Diimine-Dithiolate Nonlinear Optical Chromophores Based on Arylethylene-1,2-dithiolate and 2-Thioxothiazoline-4,5-dithiolatecitations
- 2004Ruthenium(II) carbonyl complexes containing tertiary phosphine chalcogenide ligands of the type Ph 3 PX; X=O, S, Secitations
- 2003Phosphorus-selenium heterocycles from the tetraphospholane (PhP) 4 CH 2
- 2001Synthesis of chelate complexes and the dichalcogen derivatives of the unsymmetrical diphosphine ligand Ph 2 PNHC 6 H 4 PPh 2 . Molecular Structure of [PtCl 2 (Ph 2 PNHC 6 H 4 PPh 2 )]·0.75dmso·0.75CHCl 3citations
- 2001Bridge cleavage of transition metal dimers by chelating S,N ligands. X-ray crystal structure of [Pd{SPPh 2 N=C(NH2)NH-S,N}(3-C3H5)]
- 2001The Evolution, Chemistry and Applications of Homogeneous Liquid Redox Sulfur Recovery Techniques
Places of action
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article
Spirocyclic, macrocyclic and ladder complexes of coinage metals and mercury with dichalcogeno P2N2-supported anions
Abstract
<p>Metathetical reactions of alkali–metal derivatives of the dianion [<sup>t</sup>BuN(Se)P(μ-N<sup>t</sup>Bu)<sub>2</sub>P(Se)N<sup>t</sup>Bu]<sup>2−</sup> (2Se<sup>2−</sup>) with Ag(NHC)Cl, Ag[BF<sub>4</sub>], AuCl(THT) and HgCl<sub>2</sub>, as well as the reaction of 2S<sup>2−</sup> with AuCl(THT) were investigated. The observed products all incorporate the monoprotonated ligands 2SeH<sup>− </sup>or 2SH<sup>−</sup> in a variety of structural arrangements around the metal centres, including tetrameric and trimeric macrocycles [Ag and Au (E = Se)], a ladder (Au, E = S) and a spirocycle (Hg); the ladder contains both the dianion 2S<sup>2−</sup> and the monoanion 2SH<sup>−</sup> as ligands linking three Au<sub>2</sub> units. All complexes have been characterised in the solid state by single crystal X-ray analyses and in solution by multinuclear (<sup>1</sup>H, <sup>31</sup>P and <sup>77</sup>Se) NMR spectra.</p>