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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wojciechowski, Konrad
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Topics
Publications (9/9 displayed)
- 2022Modification of a Buried Interface with Bulky Organic Cations for Highly Stable Flexible Perovskite Solar Cellscitations
- 2022Inkjet Printing of Quasi‐2D Perovskite Layers with Optimized Drying Protocol for Efficient Solar Cellscitations
- 2022Solution-processable perylene diimide-based electron transport materials as non-fullerene alternatives for inverted perovskite solar cellscitations
- 2022Solution-processable perylene diimide-based electron transport materials as non-fullerene alternatives for inverted perovskite solar cellscitations
- 2021Designing New Indene-Fullerene Derivatives as Electron-Transporting Materials for Flexible Perovskite Solar Cellscitations
- 2015Templated microstructural growth of perovskite thin films via colloidal monolayer lithographycitations
- 2015Phosphonic anchoring groups in organic dyes for solid-state solar cellscitations
- 2015Phosphonic anchoring groups in organic dyes for solid-state solar cellscitations
- 2015Highly efficient, flexible, indium-free perovskite solar cells employing metallic substratescitations
Places of action
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article
Phosphonic anchoring groups in organic dyes for solid-state solar cells
Abstract
We report the synthesis and the optoelectronic characterization of three new 4<i>H</i>-pyran-4-ylidene and thiazole derivatives (pyt) as metal-free organic dyes for solid-state dye-sensitized solar cells (DSSCs). We investigate the performance and the long-term stability of devices employing pyt dyes functionalized with carboxylic and phosphonic acids as TiO<sub>2</sub> anchoring groups. In contrast to reports on liquid electrolyte DSSCs, we show that solid-state DSSCs prepared with phosphoric pyt derivatives can achieve similar power conversion efficiency to their carboxyl analogues. We make use of the Mott–Schottky analysis and equivalent circuit models to demonstrate that a phosphonic group induces a significant increase in built-in voltage at the TiO<sub>2</sub>-hole transporter interface, which results in a higher open circuit voltage.