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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Freire, C.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2024Highly Efficient and Magnetically Recyclable Non-Noble Metal Fly Ash-Based Catalysts for 4-Nitrophenol Reductioncitations
- 2023Electrocatalytic Oxygen Reduction Reaction on 48-Tungsto-8-Phosphate Wheel Anchored on Carbon Nanomaterialscitations
- 2023Design and photo-Fenton performance of Graphene/CuS/Fe3O4 tertiary nanocomposites for Rhodamine B degradationcitations
- 2021Graphene@Metal Sulfide/Oxide Nanocomposites as Novel Photo-Fenton-like Catalysts for 4-Nitrophenol Degradationcitations
- 2019Graphene-poly(nickel complex) as novel electrochromic nanocomposite for the fabrication of a robust solid-state devicecitations
- 2018Photochromic polypropylene fibers based on UV-responsive silica@phosphomolybdate nanoparticles through melt spinning technologycitations
- 2018Heteroatom-Doped Carbon Nanomaterials as Metal-Free Catalysts for the Reduction of 4-Nitrophenolcitations
- 2017Facile synthesis of well dispersed Pd nanoparticles on reduced graphene oxide for electrocatalytic oxidation of formic acidcitations
- 2016Facile synthesis of reduced graphene oxide supported Pd@NixB/RGO nanocomposite: Novel electrocatalyst for ethanol oxidation in alkaline mediacitations
- 2016Facile synthesis of Co/RGO nanocomposite for methylene blue dye removalcitations
- 2016Novel synthesis of highly catalytic active Cu@Ni/RGO nanocomposite for efficient hydrogenation of 4-nitrophenol organic pollutantcitations
- 2016Facile synthesis of novel Co-B@Ni/RGO nanocomposite: A cost effective catalyst for improved hydrogen generation with enhanced electrochemical activitycitations
- 2015Novel synthesis of Ag@Co/RGO nanocomposite and its high catalytic activity towards hydrogenation of 4-nitrophenol to 4-aminophenolcitations
- 2015Reduction of 4-nitrophenol to 4-aminophenol using a novel Pd@NixB-SiO2/RGO nanocomposite: enhanced hydrogen spillover and high catalytic performancecitations
- 2014Tailored design of CoxMn1-xFe2O4 nanoferrites: a new route for dual control of size and magnetic propertiescitations
- 2014Gold nanoparticles decorated on Bingel-thiol functionalized multiwall carbon nanotubes as an efficient and robust catalystcitations
- 2013Silica nanoparticles functionalized with a thermochromic dye for textile applicationscitations
- 2013Electrical conductivity of LTA-zeolite in the presence of poly(vinyl alcohol) and poly(vinyl pyrrolidone) polymerscitations
- 2012Superparamagnetic MFe2O4 (M = Fe, Co, Mn) Nanoparticles: Tuning the Particle Size and Magnetic Properties through a Novel One-Step Coprecipitation Routecitations
- 2010Novel Layer-by-Layer Interfacial [Ni(salen)]-Polyelectrolyte Hybrid Filmscitations
- 2008Preparation and characterization of poly[Ni(salen)(crown receptor)]/multi-walled carbon nanotube composite filmscitations
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article
Tailored design of CoxMn1-xFe2O4 nanoferrites: a new route for dual control of size and magnetic properties
Abstract
This work reports the tailored design of novel mixed ferrite nanoparticles, CoxMn1-xFe2O4 (x = 0, 0.3, 0.7, and 1), through an optimized one-pot aqueous coprecipitation process. The influence of the substitution between Mn(II) and Co(II) and of the alkaline agent, isopropanolamine (MIPA) or NaOH, on the morphological, chemical and magnetic properties of the nanomaterials was investigated. The joint action between chemical substitution and type of alkaline agent allowed a precise tuning of the particle size, magnetic properties and inversion degree of the spinel structure. A wide range of particle dimensions (from 3 to 30 nm) and saturation magnetization (from 57 to 71 emu g(-1)) was achieved. The increase of Co(II) content from x = 0 to x = 1 led to a systematic decrease of the particle size, regardless of the base type, which could be modelled by an exponential decay function. For each Co : Mn composition, the use of MIPA instead of the traditional NaOH promoted a three times reduction of the particle size and simultaneously switched the magnetic state of the CoxMn1-xFe2O4 nanomaterials from ferromagnetic to superparamagnetic. These results constitute a step forward in the challenging quest for high-performance magnetic nanoprobes by an eco-friendly synthesis route.