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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Younesi, Reza
Uppsala University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2022Importance of Superstructure in Stabilizing Oxygen Redox in P3-Na0.67Li0.2Mn0.8O2citations
- 2022Concentrated LiFSI-Ethylene Carbonate Electrolytes and Their Compatibility with High-Capacity and High-Voltage Electrodescitations
- 2022Importance of superstructure in stabilizing oxygen redox in P3- Na0.67Li0.2Mn0.8O2citations
- 2022Importance of superstructure in stabilizing oxygen redox in P3- Na 0.67 Li 0.2 Mn 0.8 O 2citations
- 2021On the Manganese Dissolution Process from LiMn2O4 Cathode Materialscitations
- 2021Vacancy enhanced oxygen redox reversibility in P3-type magnesium doped sodium manganese oxide Na0.67Mg0.2Mn0.8O2citations
- 2021Prospects for Improved Magnesocene-Based Magnesium Battery Electrolytescitations
- 2021Importance of superstructure in stabilizing oxygen redox in P3- Na0.67Li0.2Mn0.8O2citations
- 2020Vacancy enhanced oxygen redox reversibility in P3-type magnesium doped sodium manganese oxide Na 0.67 Mg 0.2 Mn 0.8 O 2citations
- 2020Vacancy enhanced oxygen redox reversibility in P3-type magnesium doped sodium manganese oxide Na0.67Mg0.2Mn0.8O2citations
- 2020How Mn/Ni Ordering Controls Electrochemical Performance in High-Voltage Spinel LiNi0.44Mn1.56O4 with Fixed Oxygen Contentcitations
- 2020How Mn/Ni Ordering Controls Electrochemical Performance in High-Voltage Spinel LiNi0.44Mn1.56O4with Fixed Oxygen Contentcitations
- 2020How Mn/Ni Ordering Controls Electrochemical Performance in High-Voltage Spinel LiNi 0.44 Mn 1.56 O 4 with Fixed Oxygen Contentcitations
- 2020Acetonitrile‐Based Electrolytes for Rechargeable Zinc Batteriescitations
- 2019Towards room temperature operation of all-solid-state Na-ion batteries through polyester-polycarbonate-based polymer electrolytescitations
- 2017Electrochemical performance and interfacial properties of Li-metal in lithium bis(fluorosulfonyl)imide based electrolytescitations
- 2017Simple and Green Method for Fabricating V2O5·nH2O Nanosheets for Lithium Battery Application
- 2015Plasma properties during magnetron sputtering of lithium phosphorous oxynitride thin filmscitations
- 2015Capillary based Li-air batteries for in situ synchrotron X-ray powder diffraction studiescitations
- 2014Ionic conductivity and the formation of cubic CaH 2 in the LiBH 4 -Ca(BH 4 ) 2 compositecitations
- 2014Ionic conductivity and the formation of cubic CaH2 in the LiBH4-Ca(BH4)2 compositecitations
- 2014In Situ Synchrotron XRD on a Capillary Li-O2 Battery Cell
Places of action
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article
Capillary based Li-air batteries for in situ synchrotron X-ray powder diffraction studies
Abstract
For Li-air batteries to reach their full potential as energy storage system, a complete understanding of the conditions and reactions in the battery during operation is needed. To follow the reactions in situ a capillary-based Li-O2 battery has been developed for synchrotron-based in situ X-ray powder diffraction (XRPD). In this article, we present the results for the analysis of 1st and 2nd deep discharge and charge for a cathode being cycled between 2 and 4.6 V. The crystalline precipitation of Li2O2 only is observed in the capillary battery. However, there are indications of side reactions. The Li2O2 diffraction peaks grow with the same rate during charge and the development of the full width at half maximum (FWHM) is hkl dependent. The difference in the FWHM of the 100 and the 102 reflections indicate anisotropic morphology of the Li2O2 crystallites or defects along the c-axis. The effect of constant exposure of X-ray radiation to the electrolyte and cathode during charge of the battery was also investigated. X-ray exposure during charge leads to changes in the development of the intensity and the FWHM of the Li2O2 diffraction peaks. The X-ray diffraction results are supported by ex situ X-ray photoelectron spectroscopy (XPS) of discharged cathodes to illuminate non-crystalline deposited materials.