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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Leroy, Frédéric
Vrije Universiteit Brussel
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Polarization structure of nanostrip domain intersections in GeTe films
- 2024Van der Waals epitaxy of Weyl-semimetal Td-WTe2citations
- 2023Early-stage growth of GeTe on Si(111)-Sbcitations
- 2021High-throughput amplicon sequencing to assess the impact of processing factors on the development of microbial communities during spontaneous meat fermentationcitations
- 2020Dynamics of Gold Droplet Formation on SiO 2 /Si(111) Surfacecitations
- 2020Dynamics of Au-Ge liquid droplets on Ge(1 1 1) terraces: Nucleation, growth and dynamic coalescencecitations
- 2014Photoelectrochemical and electrocatalytic properties of thermally oxidized copper oxide for efficient solar fuel productioncitations
- 2010Thermal instability of silicon-on-insulator thin films measured by low-energy electron microscopycitations
- 2008Growth of Co on Au(111) studied by multiwavelength anomalous grazing-incidence small-angle x-ray scattering: From ordered nanostructures to percolated thin films and nanopillarscitations
Places of action
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article
Photoelectrochemical and electrocatalytic properties of thermally oxidized copper oxide for efficient solar fuel production
Abstract
We report the use of a facile and highly scalable synthesis process to control growth products of earth-abundant Cu-based oxides and their application in relevant photoelectrochemical and electrochemical solar fuel generation systems. Characterization of the synthesized Cu(I)/Cu(II) oxides indicates that their surface morphology and chemical composition can be simply tuned by varying two synthesis parameters (time and temperature). UV-Vis spectroscopy and impedance spectroscopy studies are performed to estimate the band structures and electronic properties of these p-type semiconductor materials. Photoelectrodes made of Cu oxides possess favorable energy band structures for production of hydrogen from water; the position of their conduction band is ≈1 V more negative than the water-reduction potential. High acceptor concentrations on the order of 1018-1019 cm-3 are obtained, producing large electric fields at the semiconductor-electrolyte interface and thereby enhancing charge separation. The highly crystalline pristine samples used as photocathodes in photoelectrochemical cells exhibit high photocurrents under AM 1.5G simulated illumination. When the samples are electrochemically reduced under galvanostatic conditions, the co-existence of the oxide with metallic Cu on the surface seems to function as an effective catalyst for the selective electrochemical reduction of CO2. © the Partner Organisations 2014.