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Khaoulani, Sohayb
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Publications (4/4 displayed)
- 2021Towards Clean and Safe Water: A Review on the Emerging Role of Imprinted Polymer-Based Electrochemical Sensorscitations
- 2021Towards Clean and Safe Water: A Review on the Emerging Role of Imprinted Polymer-Based Electrochemical Sensorscitations
- 2018Ionic transport in AgI‐HgS‐As 2 S 3 glasses: Critical percolation and modifier‐controlled domainscitations
- 2014Mercury thioarsenate glasses: a hybrid chain/pyramidal networkcitations
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article
Mercury thioarsenate glasses: a hybrid chain/pyramidal network
Abstract
<p>Mercury thioarsenate glasses (HgS)<sub>x</sub>(As<sub>2</sub>S<sub>3</sub>)<sub>1−x</sub>, 0.0 ≤<italic>x</italic>≤ 0.5, form a hybrid (HgS<sub>2/2</sub>)<sub>n</sub>chain/AsS<sub>3/2</sub>pyramidal network, highly unusual for metal chalcogenide glasses. This network is evidenced by Raman spectroscopy and DFT modelling and consistent with thermal properties. Nevertheless we cannot exclude completely the presence of a small fraction of HgS<sub>4/4</sub>tetrahedral units.</p>