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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lindfors, Tom
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Topics
Publications (13/13 displayed)
- 2022Shear exfoliated few-layer graphene and cellulose nanocrystal composite as biocompatible anode with efficient charge transfercitations
- 2020Electrochemical synthesis of 3D microstructured composite films of poly(3,4-ethylenedioxythiophene) and reduced nanographene oxidecitations
- 2020Fast high-shear exfoliation of natural flake graphite with temperature control and high yieldcitations
- 2019Reduced graphene oxide as water, carbon dioxide and oxygen barrier in plasticized poly(vinyl chloride) films
- 2017Improved water barrier properties of polylactic acid films with an amorphous hydrogenated carbon (a-C:H) coatingcitations
- 2016Few-layer graphene and polyaniline composite as ion-to-electron transducer in silicone rubber solid-contact ion-selective electrodescitations
- 2015Application of composites of graphene derivatives and conducting polymers in solid-state electrochemical sensors
- 2014Dispersible composites of exfoliated graphite and polyaniline with improved electrochemical behaviour for solid-state chemical sensor applicationscitations
- 2014Electrochemical synthesis of poly(3,4-ethylenedioxythiophene) in aqueous dispersion of high porosity reduced graphene oxidecitations
- 2014Biocomposites of Nanofibrillated Cellulose, Polypyrrole, and Silver Nanoparticles with Electroconductive and Antimicrobial Propertiescitations
- 2013Potential cycling stability of graphene and conducting polymer based composite materials for supercapacitor applications
- 2012Electropolymerization of Conducting Polymers in Graphene Oxide Solutions
- 2004The influence of lipophilic additives on the emeraldine base-emeraldine salt transition of polyanilinecitations
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article
Electrochemical synthesis of poly(3,4-ethylenedioxythiophene) in aqueous dispersion of high porosity reduced graphene oxide
Abstract
We report here the one-step electrochemical synthesis of poly(3,4-ethylenedioxythiophene) (PEDOT) in an aqueous dispersion of reduced graphene oxide (rGO). The electrochemical polymerization is carried out at 1.05 V in aqueous media in the presence of 10−2 M 3,4-ethylenedioxythiophene and 1 g L−1 rGO. Unlike composites of PEDOT and graphene oxide or poly(styrene sulfonate) which have rather smooth and non-porous surface morphologies, the scanning electron microscopy images reveal that the PEDOT composite films obtained in this work have uniformly porous and open surface morphology. X-ray photoelectron spectroscopy (XPS) showed that rGO had initially a low concentration of oxygen-containing surface groups (C : O ratio = 6.5), but both FTIR spectroscopy and XPS showed that the electropolymerization resulted in the formation of OH groups in the composite film. Characterization with cyclic voltammetry and electrochemical impedance spectroscopy demonstrates that the composite films behave almost like ideal capacitors having an areal capacitance of 12.2 mF cm−2. The composite films had a very good potential cycling stability in 0.1 M KCl with only 12.4% degradation of the capacitance in a three-electrode cell after 3000 cycles between −0.5 and 0.5 V. The degradation was higher (32.8%) in the broader potential range of −0.8 and 0.7 V.