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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Petrov, R. H. | Madrid |
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Casati, R. |
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Kočí, Jan | Prague |
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Azam, Siraj |
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Ali, M. A. |
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Rančić, M. |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Niste, Vlad
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article
WS2 nanoparticles - potential replacement for ZDDP and friction modifier additives
Abstract
In high-pressure, high-temperature sliding contacts, WS2 nanoadditives react with the metal substrate to<br/>generate 100+ nm chemical tribofilms with a layered structure and excellent tribological properties. The<br/>friction, wear and micromechanical properties of WS2 tribofilms are compared with those of tribofilms<br/>formed by the zinc dialkyldithiophosphate (ZDDP) antiwear additive and ZDDP-organic friction modifier<br/>(OFM) mixture. Nanoindentation measurements showed that WS2 generates tribofilms with higher values<br/>of hardness and Young's modulus than ZDDP and ZDDP + OFM, which explains its excellent antiwear<br/>properties. The friction performance of WS2 surpassed that of ZDDP + OFM. The striking reduction of<br/>boundary friction is credited to the layered structure of the WS2 tribofilm, with exfoliated/squashed WS2<br/>nanoparticles that fill the gaps and cover the reacted tribofilm. In view of these results, WS2 proves to be<br/>a suitable candidate for the replacement of problematic lubricant additives currently in use.