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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Styles, Mark J.
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Publications (5/5 displayed)
- 2017Fe3O4@HKUST-1 and Pd/Fe3O4@HKUST-1 as magnetically recyclable catalysts prepared via conversion from a Cu-based ceramiccitations
- 2015Positioning of the HKUST-1 metal-organic framework (Cu3(BTC)2) through conversion from insoluble Cu-based precursorscitations
- 2015Lead(II) uptake by aluminium based magnetic framework composites (MFCs) in watercitations
- 2015ZnO as an efficient nucleating agent for rapid, room temperature synthesis and patterning of Zn-based metal-organic frameworkscitations
- 2015Biomimetic mineralization of metal-organic frameworks as protective coatings for biomacromoleculescitations
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article
Positioning of the HKUST-1 metal-organic framework (Cu3(BTC)2) through conversion from insoluble Cu-based precursors
Abstract
<p>A Cu-based metal-organic framework (HKUST-1 or Cu<sub>3</sub>(BTC)<sub>2</sub>, BTC = 1,3,5-benzene tricarboxylate) has been synthesized from insoluble Cu-based precursors and positioned on substrates. Patterning of HKUST-1 was achieved through a two-step process: (1) the positioning of the insoluble Cu-based ceramic precursors on substrates using a sol-gel solution, and (2) the subsequent conversion into HKUST-1 by treatments with an alcoholic solution containing 1,3,5-benzene tricarboxylic acid (H<sub>3</sub>BTC) at room temperature for 10 min. This technique has been found to be suitable for both inorganic and polymeric substrates. The HKUST-1 pattern on a polymer film can be easily bent without affecting the positioned MOFs crystals. This approach would allow for versatile and practical applications of MOFs in multifunctional platforms where the positioning of MOFs is required.</p>