| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Sinha, Chittaranjan
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Synthesis, antimicrobial activity and molecular docking of di‐ and triorganotin (IV) complexes with thiosemicarbazide derivativescitations
- 2024New Tin (IV) and Organotin (IV) Complexes with a Hybrid Thiosemicarbazone/Hydrazone Ligand: Synthesis, Crystal Structure, and Antiproliferative Activitycitations
- 2024New tin (IV) and organotin (IV) complexes with a hybrid thiosemicarbazone/hydrazone ligand: synthesis, crystal structure and antiproliferative activitycitations
- 2023Strategy for the improvement of electrical conductivity of a 3D Zn(<scp>ii</scp>)-coordination polymer doubly bridged by mesaconato and pyridyl-isonicotinoyl hydrazide based Schottky diode devicecitations
- 2023Designing of a Zn(<scp>ii</scp>)-isonicotinohydrazido thiophenyl based 2D coordination polymer: structure, augmented photoconductivity and superior biological activitycitations
- 2022A novel synthesis of graphene oxide-titanium dioxide (GO-TiO<sub>2</sub>) and graphene oxide-zinc oxide (GO-ZnO) nanocomposites and their application as effective, reusable photocatalysts for degradation of methylene blue (MB) dyecitations
- 2019A Phenyl Thioether‐Based Probe: Zn<sup>2+</sup> Ion Sensor, Structure Determination and Live Cell Imaging<sup>†</sup>citations
- 2019Enhancement of electrical conductivity due to structural distortion from linear to nonlinear dicarboxylato-bridged Zn(II) 1D-coordination polymerscitations
- 2015An enolato-bridged dinuclear Cu(II) complex with a coumarin-assisted precursor: a spectral, magnetic and biological studycitations
- 2015A 2-D coordination polymer incorporating cobalt(II), 2-sulfoterephthalate and the flexible bridging ligand 1,3-di(4-pyridyl)propanecitations
- 2014A mixed valent heterometallic CuII/NaI coordination polymer with sodium-phenyl bondscitations
Places of action
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article
A 2-D coordination polymer incorporating cobalt(II), 2-sulfoterephthalate and the flexible bridging ligand 1,3-di(4-pyridyl)propane
Abstract
<p>The cobalt derivative {[Co<sub>3</sub>(2-stp)<sub>2</sub>(dpp)<sub>4</sub>]·2H<sub>2</sub>O}<sub>n</sub> (1) has been hydro(solvo)thermally synthesised by combining sodium 2-sulfoterephthalic acid (2-stpH<sub>2</sub>Na) and divalent cobalt nitrate in presence of the flexible N-donor co-ligand dpp (1,3-di(4-pyridyl)propane). Single-crystal X-ray diffraction shows that 1 is a twodimensional coordination polymer with carboxylate and sulfonate oxygens and pyridyl nitrogens coordinated to the two symmetry independent octahedral cobalt(II) centres. UV-Vis, magnetic and EPR studies show that the cobalt(II) centres are high-spin. Compound 1 proved to be robust to the removal of the solvent water molecules, which was achieved by heating the sample to yield the desolvated complex {[Co<sub>3</sub>(2-stp)<sub>2</sub>(dpp)<sub>4</sub>]}<sub>n</sub> (2). 2 was also characterised by single-crystal X-ray diffraction at 331 K. Gas sorption studies on this material showed only surface binding of N<sub>2</sub> and modest uptake for CO<sub>2</sub>. The crystallographic analysis also shows that upon desolvation, the flexible propyl groups of the dpp ligand adjust their positions, reducing the potentially accessible void volumes and accounting for the gas adsorption results.</p>