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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sun, Xiufu
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2023Solid Oxide Electrochemical Cells for Nitrogen and Oxygen Production
- 2022Metal Supported Electrolysis Cellscitations
- 2021Ni migration in solid oxide cell electrodes:Review and revised hypothesiscitations
- 2021Ni migration in solid oxide cell electrodes: Review and revised hypothesiscitations
- 2021Ni migration in solid oxide cell electrodes: Review and revised hypothesiscitations
- 2020Co-electrolysis of steam and carbon dioxide in large area solid oxide cells based on infiltrated mesoporous oxygen electrodescitations
- 2020Metal Supported SOFCs for Mobile Applications using Hydrocarbon Fuelscitations
- 2020Review of Ni migration in SOC electrodes
- 2020Review of Ni migration in SOC electrodes
- 2019Comprehensive Hypotheses for Degradation Mechanisms in Ni-Stabilized Zirconia Electrodescitations
- 2019Comprehensive Hypotheses for Degradation Mechanisms in Ni-Stabilized Zirconia Electrodescitations
- 2019Internal reforming on Metal supported SOFCscitations
- 2018Diffusion rates of reactants and components in solid oxide cells
- 2017Investigation of a Spinel-forming Cu-Mn Foam as an Oxygen Electrode Contact Material in a Solid Oxide Cell Single Repeating Unitcitations
- 2014TOF-SIMS characterization of impurity enrichment and redistribution in solid oxide electrolysis cells during operationcitations
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article
TOF-SIMS characterization of impurity enrichment and redistribution in solid oxide electrolysis cells during operation
Abstract
TOF-SIMS analyses of state-of-the-art high temperature solid oxide electrolysis cells before and after testing under different operating conditions were performed. The investigated cells consist of an yttria stabilized zirconia (YSZ) electrolyte, a La1-xSrxMnO3-δ composite anode and a Ni-YSZ cermet cathode. The surfaces and cross-sections of the cells were analyzed, and several elemental impurities like Si, Ca and Na were identified and spatially mapped and their enrichment and migration during operation is reported. With advancing operation time, the concentration of these elements, especially Na and Ca, increases. For Si, a concentration gradient is found from the gas inlet to the gas outlet. Additionally, a loss of Ni percolation in the active cathode is observed in the same area where the Si enrichment is found. Based on the obtained TOF-SIMS results, the influence of the operating conditions on degradation is discussed.