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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Cordier, Stéphane
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (48/48 displayed)
- 2024Effect of an Aromatic Sulfonate Ligand on the Photovoltaic Performance of Molybdenum Cluster-Sensitized Solar Cellscitations
- 2023Flexible and Transparent Luminescent Cellulose-Transition Metal Cluster Compositescitations
- 2023Enhanced NH3 Sensing Performance of Mo Cluster-MoS2 Nanocomposite Thin Films via the Sulfurization of Mo6 Cluster Iodides Precursorcitations
- 2023From Solid-State Cluster Compounds to Functional PMMA-Based Composites with UV and NIR Blocking Properties, and Tuned Hues
- 2022High performance {Nb5TaX12}@PVP (X = Cl, Br) cluster-based nanocomposites coatings for solar glazing applicationscitations
- 2022A review on functional nanoarchitectonics nanocomposites based on octahedral metal atom clusters (Nb-6, Mo-6, Ta-6, W-6, Re-6): inorganic 0D and 2D powders and filmscitations
- 2022Surface Plasmon Tunability of Core-Shell Au@Mo(6) Nanoparticles by Shell Thickness Modificationcitations
- 2022Controlling the Deposition Process of Nanoarchitectonic Nanocomposites Based on {Nb(6-x)Ta(x)X(i)(12)}(n+) Octahedral Cluster-Based Building Blocks (X(i) = Cl, Br; 0 ≤ x ≤ 6, n = 2, 3, 4) for UV-NIR Blockers Coating Applicationscitations
- 2022Reentrant structural and optical properties of organic-inorganic hybrid metal cluster compound ((n-C4H9)(4)N)(2)[(Mo6Br8Br6a)-Br-i]citations
- 2022Nanoarchitectonics of Glass Coatings for Near-Infrared Shielding: From Solid-State Cluster-Based Niobium Chlorides to the Shaping of Nanocomposite Filmscitations
- 2022Reentrant structural and optical properties of organic-inorganic hybrid metal cluster compound ((n-C4H9)(4)N)(2)[(Mo6Bri8Br6a)]citations
- 2022Joint Venture of Metal Cluster and Amphiphilic Cationic Minidendron Resulting in Near Infrared Emissive Lamellar Ionic Liquid Crystalscitations
- 2022Light-dependent ionic-electronic conduction in an amorphous octahedral molybdenum cluster thin filmcitations
- 2021Poly(dimethylsiloxane) functionalized with complementary organic and inorganic emitters for the design of white emissive waveguidescitations
- 2021Expanding the Toolbox of Octahedral Molybdenum Clusters and Nanocomposites Made Thereof: Evidence of Two-Photon Absorption Induced NIR Emission and Singlet Oxygen Productioncitations
- 2021Synthesis of novel hexamolybdenum cluster-functionalized copper hydroxide nanocomposites and its catalytic activity for organic molecule degradationcitations
- 2020Structure, microstructure and thermoelectric properties of germanite-type Cu22Fe8Ge4S32 compoundscitations
- 2020Structure, microstructure and thermoelectric properties of germanite-type Cu22Fe8Ge4S32 compoundscitations
- 2020Zn-Al layered double hydroxide-based nanocomposite functionalized with an octahedral molybdenum cluster exhibiting prominent photoactive and oxidation propertiescitations
- 2020Time-Resolved In Situ Neutron Diffraction Study of Cu22Fe8Ge4S32 Germanite: A Guide for the Synthesis of Complex Chalcogenidescitations
- 2020Preparation and characterization of hollow silica nanocomposite functionalized with UV absorbable molybdenum clustercitations
- 2020Zn-Al Layered Double Hydroxide Film Functionalized by a Luminescent Octahedral Molybdenum Cluster: Ultraviolet-Visible Photoconductivity Responsecitations
- 2020Switchable Two-Dimensional Waveguiding Abilities of Luminescent Hybrid Nanocomposites for Active Solar Concentratorscitations
- 2019Transparent functional nanocomposite films based on octahedral metal clusters synthesis by electrophoretic deposition process and characterizationcitations
- 2019ITO@SiO2 and ITO@{M6Br12}@SiO2 (M = Nb, Ta) nanocomposite films for ultraviolet-near infrared shieldingcitations
- 2018Elastic softness of hybrid lead halide perovskites
- 2018Elastic softness of hybrid lead halide perovskitescitations
- 2018Lord of The Crowns A New Precious in the Kingdom of Clustomesogenscitations
- 2018Low-frequency Raman spectroscopy and elastic softness of hybrid lead halide perovskites
- 2018Low dimensional solids based on Mo-6 cluster cyanides and Mn2+, Mn3+ or Cd2+ metal ions crystal chemistry, magnetic and optical propertiescitations
- 2017Designing a Thermoelectric Copper-Rich Sulfide from a Natural Mineral: Synthetic Germanite Cu22Fe8Ge4S32citations
- 2017High temperature neutron powder diffraction study of the Cu12Sb4S13 and Cu4Sn7S16 phasescitations
- 2017Transparent tantalum cluster-based UV and IR blocking electrochromic devicescitations
- 2017Simulation of crystal and electronic structures of octahedral molybdenum cluster complex compound Cs-2[Mo6Cl14] using various DFT functionalscitations
- 2016Versatility of the ionic assembling method to design highly luminescent PMMA nanocomposites containing [M6Qi8La6]n- octahedral nano-building blockscitations
- 2016Time-gated luminescence bioimaging with new luminescent nanocolloids based on [Mo6I8(C2F5COO)(6)](2-) metal atom clusterscitations
- 2016Efficient active waveguiding properties of Mo6 nano-cluster-doped polymer nanotubes
- 2016Plastic crystal behavior, tight-binding modelling and low energy phonon spectroscopy in hybrid perovskites crystals
- 2016Inorganic Molybdenum Clusters as Light-Harvester in All Inorganic Solar Cells: A Proof of Conceptcitations
- 2016Facile design of red-emitting waveguides using hybrid nanocomposites made of inorganic clusters dispersed in SU8 photoresist hostcitations
- 2015Surface immobilization of Mo6I8 octahedral cluster cores on functionalized amorphous carbon using a pyridine complexation strategycitations
- 2015Tuned red NIR phosphorescence of polyurethane hybrid composites embedding metallic nanoclusters for oxygen sensingcitations
- 2014Deep red luminescent hybrid copolymer materials with high transition metal cluster contentcitations
- 2013One-pot synthesis of gold nanoparticle/molybdenum cluster/graphene oxide nanocomposite and its photocatalytic activitycitations
- 2013Color control in coaxial two-luminophore nanowires.citations
- 2010Fine tuning of emission through the engineering of colloidal crystalscitations
- 2008When “metal atom clusters” meet ZnO Nanocrystals: A ((n-C4H9)4N)2Mo6Br14@ZnO hybrid.citations
- 2006Mn5Si3-type host-interstitial boron rare-earth metal silicide compounds RE5Si3: Crystal structures, physical properties and theoretical considerationscitations
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article
Deep red luminescent hybrid copolymer materials with high transition metal cluster content
Abstract
The hybrid strategy is a powerful approach to design functional materials by combining inorganic dyes with an organic matrix. However, introducing high contents of inorganic species within the hybrid material is a real challenge that requires a perfect balance between the interactions of both components to avoid mainly phase segregation problems. Based on our demonstration on an anionic molybdenum cluster, we present a general method to introduce high contents of such class of nanometre sized inorganic molecular deep red dyes in a polymer matrix. Our strategy exploits the physical interactions between the organic and inorganic parts of the hybrid material and allows a high cluster rate to be introduced (up to 50 wt%) in the polymer matrix. The resulting hybrids are remarkably stable even after several months of ageing. Moreover, the Mo clusters maintain their intrinsic deep red luminescence properties while the polymer organic matrix fully maintains its processability, thanks to the di-anionic character of the Mo6 clusters. Such materials show promising prospects in applications needing deep red emitters.