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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Martucci, Alessandro
University of Padua
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Accurate prediction of the optical properties of nanoalloys with both plasmonic and magnetic elementscitations
- 2023Rapid laser-induced low temperature crystallization of thermochromic VO2 sol-gel thin filmscitations
- 2023Determination of the Optical Constants of Gold Nanoparticles from Thin-Film Spectracitations
- 2019Functionalization of Titanates–Silk Nanocomposites via Cation Exchange for Optical Applicationscitations
- 2018SiO2-SnO2:Er3+ transparent glass-ceramics: fabrication and photonic assessmentcitations
- 2018Nano-structured aluminum surfaces for dropwise condensationcitations
- 2015Fast One-Pot Synthesis of MoS2/Crumpled Graphene p-n Nanonjunctions for Enhanced Photoelectrochemical Hydrogen Productioncitations
- 2013Xylene sensing properties of aryl-bridged polysilsesquioxane thin films coupled to gold nanoparticlescitations
- 2012Highly luminescent and temperature stable quantum dot thin-films based on a ZnS compositecitations
- 2011Functional three-dimensional nonlinear nanostructures in a gold ion nanocomposite
- 2008Optical gas sensing of TiO2 and TiO2/Au nanocomposite thin filmscitations
- 2004Nanostructured sol-gel silica thin films doped with NiO and SnO2 for gas sensing applicationscitations
Places of action
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article
Xylene sensing properties of aryl-bridged polysilsesquioxane thin films coupled to gold nanoparticles
Abstract
Surface plasmon resonance gas sensors based on organic–inorganic hybrid thin films coupled to gold nanoparticles were fabricated and tested against the detection of xylene at the concentration of 30 ppm. Such nanocomposites are prepared either by dispersing Au nanoparticles inside an aryl-bridged polysilsesquioxane system, synthesized via a sol–gel process, or by depositing an aryl-bridged polysilsesquioxane film on Au nanoparticle sub-monolayers. Ultra-high-vacuum temperature programmed desorption of xylene on both the aryl-bridged polysilsesquioxane films and the nanocomposite Au/hybrid system was investigated, resulting in an interaction energy between the sensitive film and the gas molecules in the 38–139 kJ mol−1 range. The functional activity of the nanostructured composites as xylene gas optical sensors was tested monitoring gold localized surface plasmon resonance, and was shown to be reversible. The detection sensitivity was calculated in 0.1 ppb through a calibration procedure in the 16–30 ppm range, and a threshold limit of detection of 265 ppb xylene was estimated as three standard deviations of the baseline noise. Typical response and regeneration times are of one min and about one ten of minutes, respectively.