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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Rizzi, Gian Andrea
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Topics
Publications (15/15 displayed)
- 2024Pt-decorated graphitic carbon nitride on carbon paper by x-ray photoelectron spectroscopycitations
- 2023Insights into the Photoelectrocatalytic Behavior of gCN-Based Anode Materials Supported on Ni Foamscitations
- 2023Fe2O3-graphitic carbon nitride nanocomposites analyzed by XPScitations
- 2018Density Functional Theory (DFT) and Experimental Evidences of Metal–Support Interaction in Platinum Nanoparticles Supported on Nitrogen- and Sulfur-Doped Mesoporous Carbons: Synthesis, Activity, and Stabilitycitations
- 2018Interfacial Morphology Addresses Performance of Perovskite Solar Cells Based on Composite Hole Transporting Materials of Functionalized Reduced Graphene Oxide and P3HTcitations
- 2018Probing the correlation between Pt-support interaction and oxygen reduction reaction activity in mesoporous carbon materials modified with Pt-N active sitescitations
- 2017Ag-Vanadates/GO Nanocomposites by Aerosol-Assisted Spray Pyrolysis: Preparation and Structural and Electrochemical Characterization of a Versatile Materialcitations
- 2016VO <sub>2</sub> /V <sub>2</sub> O <sub>5</sub> :Ag Nanostructures on a DVD as Photoelectrochemical Sensorscitations
- 2016Cu2O/TiO2 heterostructures on a DVD as easy&cheap photoelectrochemical sensorscitations
- 2015Comparison between the Oxygen Reduction Reaction Activity of Pd<sub>5</sub>Ce and Pt<sub>5</sub>Ce: The Importance of Crystal Structurecitations
- 2013Xylene sensing properties of aryl-bridged polysilsesquioxane thin films coupled to gold nanoparticlescitations
- 2005Epitaxial TiO2 nanoparticles on Pt(111): a structural study by photoelectron diffraction and scanning tunneling microscopycitations
- 2005Ultrathin TiO<i><sub>x</sub></i> Films on Pt(111): A LEED, XPS, and STM Investigationcitations
- 2003Growth of NiO ultrathin films on Pd(100) by post-oxidation of Ni films: the effect of pre-adsorbed oxygencitations
- 2000An X-ray photoelectron diffraction structural characterisation of epitaxial ultrathin RuO2/TiO2(110) films obtained by decomposition of Ru3(CO)12citations
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article
Xylene sensing properties of aryl-bridged polysilsesquioxane thin films coupled to gold nanoparticles
Abstract
Surface plasmon resonance gas sensors based on organic–inorganic hybrid thin films coupled to gold nanoparticles were fabricated and tested against the detection of xylene at the concentration of 30 ppm. Such nanocomposites are prepared either by dispersing Au nanoparticles inside an aryl-bridged polysilsesquioxane system, synthesized via a sol–gel process, or by depositing an aryl-bridged polysilsesquioxane film on Au nanoparticle sub-monolayers. Ultra-high-vacuum temperature programmed desorption of xylene on both the aryl-bridged polysilsesquioxane films and the nanocomposite Au/hybrid system was investigated, resulting in an interaction energy between the sensitive film and the gas molecules in the 38–139 kJ mol−1 range. The functional activity of the nanostructured composites as xylene gas optical sensors was tested monitoring gold localized surface plasmon resonance, and was shown to be reversible. The detection sensitivity was calculated in 0.1 ppb through a calibration procedure in the 16–30 ppm range, and a threshold limit of detection of 265 ppb xylene was estimated as three standard deviations of the baseline noise. Typical response and regeneration times are of one min and about one ten of minutes, respectively.