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| Naji, M. |
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| Motta, Antonella |
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| Azevedo, Nuno Monteiro |
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Webster, Ruth
University of Cambridge
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2023The Complex Reactivity of [(salen)Fe]2(μ-O) with HBpin and its Implications in Catalysiscitations
- 2015Titanium pyridonates for the homo- and copolymerization of rac-lactide and ε-caprolactonecitations
- 2014Random copolymerisations catalysed by simple titanium α-amino acid complexescitations
- 2013Titanium pyridonates and amidates: novel catalysts for the synthesis of random copolymerscitations
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article
Random copolymerisations catalysed by simple titanium α-amino acid complexes
Abstract
α-Amino acid complexes of titanium have been applied in the synthesis of biopolymers. The complexes can be prepared under mild conditions often using hydrous procedures and result in the preparation of polylactide and polycaprolactone without the need for rigorous drying and air-sensitive handling. The complexes also prove to be excellent initiators for the synthesis of random copolymers: they are rare examples of completely air stable designed catalysts to undertake such a transformation. The composition and thermal properties of the random copolymers are also investigated.