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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zhang, Xin
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2023Surface Modulation via Conjugated Bithiophene Ammonium Salt for Efficient Inverted Perovskite Solar Cellscitations
- 2022An amorphous sodium aluminate hydrate phase mediates aluminum coordination changes in highly alkaline sodium hydroxide solutionscitations
- 2022Niobium and Tantalum complexes derived from the acids Ph 2 C(X)CO 2 H (X = OH, NH 2 ): synthesis, structure and ROP capabilitycitations
- 2021Alkoxy-functionalized schiff-base ligation at aluminum and zinc: Synthesis, structures and rop capabilitycitations
- 2016InGaN nanowires with high InN molar fraction: growth, structural and optical propertiescitations
- 2016Agromining: producing Ni salts from the biomass of hyperaccumulator plants
- 2015Complexities in the Molecular Spin Crossover Transitioncitations
- 2014Changing molecular band offsets in polymer blends of (P3HT/P(VDF-TrFE)) poly(3-hexylthiophene) and poly(vinylidene fluoride with trifluoroethylene) due to ferroelectric polingcitations
- 2014Substrate and temperature dependence of the formation of the Earth abundant solar absorber Cu2ZnSnS4 by ex situ sulfidation of cosputtered Cu-Zn-Sn filmscitations
- 2013Polyphenols grafting to bioactive glasses and glass-ceramics
- 2013Resonant photoemission and spin polarization of Co1-xFe xS2citations
- 2012Comparison of ultrasonic reflectometry and FTIR analysis for thermal ageing effect detection for paint films on steel plates
- 2009Carrier dynamics and quantum confinement in type II ZB-WZ InP nanowire homostructures
- 2008High purity GaAs nanowires free of planar defectscitations
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article
Changing molecular band offsets in polymer blends of (P3HT/P(VDF-TrFE)) poly(3-hexylthiophene) and poly(vinylidene fluoride with trifluoroethylene) due to ferroelectric poling
Abstract
<p>Photoelectron emission and inverse photoemission spectroscopy studies of polymer blends of poly(vinylidene fluoride (70%)-trifluoroethylene (30%)) P(VDF-TrFE 70 : 30) and regio-regular poly(3-hexylthiophene) (P3HT) provide evidence of changes in the molecular band offsets as a result of changes in the ferroelectric polarization in P(VDF-TrFE). Investigation of the blends with higher concentrations of the semiconducting P3HT component revealed that the organic semiconductor component of the blend dominates the electronic structure in the vicinity of the chemical potential. Specifically, the states of P3HT at the conduction band minimum and valence band maximum fall within the HOMO-LUMO gap of the dielectric ferroelectric P(VDF-TrFE) but the P3HT does not exhibit a change in the molecular band offset with respect to the Fermi level or band bending with polarization reversal, unlike P(VDF-TrFE).</p>