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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Voet, Vincent S. D.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2024Innovative Approaches for Manufacturing Epoxy-Modified Wood and Cellulose Fiber Composites
- 2024Enzymatic bulk synthesis, characterization, rheology, and biodegradability of biobased 2,5-bis(hydroxymethyl)furan polyesterscitations
- 2023The effect of size and delignification on the mechanical properties of polylactic acid (PLA) biocomposites reinforced with wood fibres via extrusioncitations
- 2020Photopolymer Resins with Biobased Methacrylates Based on Soybean Oil for Stereolithographycitations
- 2018Biobased Acrylate Photocurable Resin Formulation for Stereolithography 3D Printingcitations
- 2015Bioinspired synthesis of well-ordered layered organic-inorganic nanohybridscitations
- 2015Bioinspired synthesis of well-ordered layered organic-inorganic nanohybrids:Mimicking the natural processing of nacre by mineralization of block copolymer templatescitations
- 2014Double-crystalline PLLA-b-PVDF-b-PLLA triblock copolymerscitations
- 2014Double-crystalline PLLA- b -PVDF- b -PLLA triblock copolymers:preparation and crystallizationcitations
- 2014Well-Defined Copolymers Based on Poly(vinylidene fluoride):From Preparation and Phase Separation to Applicationcitations
- 2014Well-Defined Copolymers Based on Poly(vinylidene fluoride)citations
- 2014Gyroid Nickel Nanostructures from Diblock Copolymer Supramoleculescitations
- 2014Gyroid Nickel Nanostructures from Diblock Copolymer Supramoleculescitations
- 2013Poly(vinylidene fluoride)/nickel nanocomposites from semicrystalline block copolymer precursorscitations
- 2013Poly(vinylidene fluoride)/nickel nanocomposites from semicrystalline block copolymer precursorscitations
- 2013Block copolymer route towards poly(vinylidene fluoride)/poly(methacrylic acid)/nickel nanocompositescitations
- 2013Block copolymer route towards poly(vinylidene fluoride)/poly(methacrylic acid)/nickel nanocompositescitations
- 2012Preparation and self-assembly of two-length-scale A-b-(B-b-A)(n)-b-B multiblock copolymerscitations
- 2012Preparation and self-assembly of two-length-scale A-b-(B-b-A)(n)-b-B multiblock copolymerscitations
Places of action
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article
Block copolymer route towards poly(vinylidene fluoride)/poly(methacrylic acid)/nickel nanocomposites
Abstract
<p>PVDF-based block copolymers have been employed as precursors for the construction of PVDF/PMAA/Ni nanocomposites. New poly(tert-butyl methacrylate)-block-poly(vinylidene fluoride)-block-poly(tert-butyl methacrylate) (PtBMA-b-PVDF-b-PtBMA) triblock copolymers were synthesized via atom transfer radical polymerization (ATRP) of tBMA from chlorine-terminated PVDF macroinitiators. The alternating crystalline-amorphous lamellar nanostructure and the spherulitic microstructure indicate the dominant role of crystallization of the PVDF segments during structure formation. The polar beta-crystalline phase of PVDF has been detected within the block copolymer films. Hydrolysis of the tBMA segments and subsequent backfilling of the remaining polymer template with nickel through electroless metal deposition generated PVDF/PMAA/Ni nanocomposites. The beta-polymorph was preserved during hydrolysis and electroless plating, as well as the lamellar morphology.</p>