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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ihiawakrim, Dris
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2024Ultrasonic chemical synthesis of zinc-manganese ferrites with improved magnetic properties.citations
- 2024Tailoring the pore structure of iron oxide core@stellate mesoporous silica shell nanocomposites: effects on MRI and magnetic hyperthermia properties and applicability to anti-cancer therapiescitations
- 2022A detailed investigation of the core@shell structure of exchanged coupled magnetic nanoparticles after performing solvent annealingcitations
- 2022TiO2 supported Co catalysts for the hydrogenation of γ-valerolactone to 2methyltetrahydrofuran: influence of the supportcitations
- 2022Shedding light on functional hybrid nanocomposites 19th century paint mediumcitations
- 2021Versatile template-directed synthesis of gold nanocages with a predefined number of windowscitations
- 2020Quantitative Analysis of the Specific Absorption Rate Dependence on the Magnetic Field Strength in ZnxFe3−xO4 Nanoparticlescitations
- 2020Efficiency of pyoverdines in iron removal from flocking asbestos waste: An innovative bacterial bioremediation strategycitations
- 2019Study by advanced transmission electron microscopy techniques fragile materials
- 2019The effect of basic pH on the elaboration of ZnFe2O4 nanoparticles by co-precipitation method: Structural, magnetic and hyperthermia characterizationcitations
- 2019The effect of basic pH on the elaboration of ZnFe2O4 nanoparticles by co-precipitation method: Structural, magnetic and hyperthermia characterizationcitations
- 2018High pressures pathway toward boron-based nanostructured solidscitations
- 2018High pressures pathway toward boron-based nanostructured solidscitations
- 2016Metal nanoparticle mediated space charge and its optical control in an organic hole-only devicecitations
- 2016Surface plasmon resonance of an individual nano-object on an absorbing substrate : quantitative effects of distance and 3D orientationcitations
- 2016Surface plasmon resonance of an individual nano-object on an absorbing substrate : quantitative effects of distance and 3D orientationcitations
- 2016Advanced three dimensional characterization of silica-based ultraporous materialscitations
- 2014Magnetic Properties of Mono- and Multilayer Assemblies of Iron Oxide Nanoparticles Promoted by SAMscitations
- 2013A single-stage functionalization and exfoliation method for the production of graphene in water: stepwise construction of 2D-nanostructured composites with iron oxide nanoparticlescitations
- 2013A single-stage functionalization and exfoliation method for the production of graphene in water: stepwise construction of 2D-nanostructured composites with iron oxide nanoparticlescitations
- 2012Hexahistidine-Tagged Single-Walled Carbon Nanotubes (His6-tagSWNTs): A Multifunctional Hard Template for Hierarchical Directed Self-Assembly and Nanocomposite Constructioncitations
Places of action
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article
A single-stage functionalization and exfoliation method for the production of graphene in water: stepwise construction of 2D-nanostructured composites with iron oxide nanoparticles
Abstract
A practically simple top-down process for the exfoliation of graphene (GN) and few-layer graphene (FLG) from graphite is described. We have discovered that a biocompatible amphiphilic pyrene-based hexahistidine peptide is able to exfoliate, functionalize, and dissolve few layer graphene flakes in pure water under exceptionally mild, sustainable and virtually innocuous low intensity cavitation conditions. Large area functionalized graphene flakes with the hexahistidine oligopeptide (His(6)-TagGN = His(6)@GN) have been produced efficiently at room temperature and characterized by TEM, Raman, and UV spectroscopy. Conductivity experiments carried out on His(6)-TagGN samples revealed superior electric performances as compared to reduced graphene oxide (rGO) and non-functionalized graphene, demonstrating the non-invasive features of our non-covalent functionalization process. We postulated a rational exfoliation mechanism based on the intercalation of the peptide amphiphile under cavitational chemistry. We also demonstrated the ability of His(6)-TagGN nanoassemblies to self-assemble spontaneously with inorganic iron oxide nanoparticles generating magnetic two-dimensional (2D) His(6)-TagGN/Fe3O4 nanocomposites under mild and non-hydrothermal conditions. The set of original experiments described here open novel perspectives in the facile production of water dispersible high quality GN and FLG sheets that will improve and facilitate the interfacing, processing and manipulation of graphene for promising applications in catalysis, nanocomposite construction, integrated nanoelectronic devices and bionanotechnology.