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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Dreyer, Christian
Technical University of Applied Sciences Wildau
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2023UV LED Curable Perfluoropolyether (PFPE)-Urethane Methacrylate Transparent Coatings for Photonic Applications: Synthesis and Characterizationcitations
- 2021Erratum to: Optical nanocomposites containing low refractive index MgF2 nanoparticles
- 2021Optical nanocomposites containing low refractive index MgF2 nanoparticlescitations
- 2021SiO2 Nanoparticles-Acrylate Formulations for Core and Cladding in Planar Optical Waveguidescitations
- 2020Novel UV-transparent 2-component polyurethane resin for chip-on-board LED micro lensescitations
- 2020Reaction-to-fire parameters of CE/epoxy blend-based CF/FF and BF/FF hybrid compositescitations
- 2013Metal fluoride-based transparent nanocomposites with low refractive indicescitations
- 2003New triazine containing polymers for use in integrated opticscitations
Places of action
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article
Metal fluoride-based transparent nanocomposites with low refractive indices
Abstract
The utilisation of magnesium and aluminium fluoride nanoparticles in the preparation of transparent composites leading to materials with superior properties was investigated. Nanoscopic magnesium and aluminium fluoride has been prepared by the fluorolytic sol-gel route from the alkoxides and was surface modified by the reaction with trifluoroacetic acid or perfluorobutyric acid. IR spectroscopic experiments of the xerogels and crystal structure analysis of a trinuclear [Mg-3(mu F-3)(mu-TFA)(6)(OCH3)(2)(py)](3-) luster unit indicate that the carboxylate group is bound to the particle surface in a monodentate or bidentate bridging fashion. These particles were successfully incorporated into acrylate polymers with up to 40 wt% content to give fully transparent material. Ellipsometry and m-line measurements of thin films show the reduction of the refractive index of composite films with increasing metal fluoride filler content.