693.932 PEOPLE
| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Petrov, R. H. | Madrid |
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| Casati, R. |
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| Kočí, Jan | Prague |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Raja, Robert
University of Southampton
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2023Using small angle neutron scattering to explore porosity, connectivity and accessibility, towards optimised hierarchical solid acid catalystscitations
- 2022New insights in establishing the structure-property relations of novel plasmonic nanostructures for clean energy applicationscitations
- 2021Rational design and application of covalent organic frameworks for solar fuel productioncitations
- 2020Combining photocatalysis and optical fibre technology towards improved microreactor design for hydrogen generation with metallic nanoparticlescitations
- 2020Incorporating metal organic frameworks within microstructured optical fibers toward scalable photoreactorscitations
- 2017Heterogeneous zeotype catalysts for the direct utilisation of CO2
- 2017The molecular design of active sites in nanoporous materials for sustainable catalysiscitations
- 2013Investigating site-specific interactions and probing their role in modifying the acid-strength in framework architecturescitations
- 2009Designed nanoporous solids for the green production of vitamins, fine chemicals and renewable nylonscitations
Places of action
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article
Investigating site-specific interactions and probing their role in modifying the acid-strength in framework architectures
Abstract
The ability to adroitly tailor acid-strength using specifically-engineered bimetallic nanoporous materials has been investigated with a view to exploiting their potential in solid-acid catalysed transformations. Further, it has been demonstrated that through site-specific interactions, extra-framework zinc ions can suitably modify the acidity of Brønsted acid sites, to stimulate diverse catalytic responses, when combined with isomorphously-substituted framework metal cations within porous architectures, for the Beckmann rearrangement of cyclohexanone oxime and in the isopropylation of benzene.