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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Linder, Markus B.
Aalto University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Molecular Engineering of a Spider Silk and Mussel Foot Hybrid Protein Gives a Strong and Tough Biomimetic Adhesivecitations
- 2023Pulling and analyzing silk fibers from aqueous solution using a robotic devicecitations
- 2023Pulling and analyzing silk fibers from aqueous solution using a robotic devicecitations
- 2022Recombinant Spider Silk Protein and Delignified Wood Form a Strong Adhesive Systemcitations
- 2022Recombinant Spider Silk Protein and Delignified Wood Form a Strong Adhesive Systemcitations
- 2020Three-Dimensional Printed Cell Culture Model Based on Spherical Colloidal Lignin Particles and Cellulose Nanofibril-Alginate Hydrogelcitations
- 2020Methyl cellulose/cellulose nanocrystal nanocomposite fibers with high ductilitycitations
- 2019Binding Forces of Cellulose Binding Modules on Cellulosic Nanomaterialscitations
- 2018Modification of carbon nanotubes by amphiphilic glycosylated proteinscitations
- 2018Self-Coacervation of a Silk-Like Protein and Its Use As an Adhesive for Cellulosic Materialscitations
- 2015Modular Architecture of Protein Binding Units for Designing Properties of Cellulose Nanomaterialscitations
- 2015Enhanced plastic deformations of nanofibrillated cellulose film by adsorbed moisture and protein-mediated interactionscitations
- 2014Structural characterization and tribological evaluation of quince seed mucilagecitations
- 2013The role of hemicellulose in nanofibrillated cellulose networkscitations
- 2013Drug release from nanoparticles embedded in four different nanofibrillar cellulose aerogelscitations
- 2012Adhesion and tribological properties of hydrophobin proteins in aqueous lubrication on stainless steel surfacescitations
Places of action
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article
The role of hemicellulose in nanofibrillated cellulose networks
Abstract
Cellulose nanofibrils show remarkable properties with applications in several fields of materials science, such as for composites, hydrogels, aerogels, foams, and coatings. Cellulose nanofibrils are typically produced by mechanical and enzymatic processing leading to fibrils having a width in the nanometer range and very high aspect ratios. The formation of percolating networks and interactions between fibrils lead to useful properties in for example gel formation and composites. In this work we studied how the residual xylan that is found in cellulose nanofibrils that have been produced from hardwood pulp affects these properties. We used enzymatic hydrolysis to specifically remove xylan and studied rheological properties, morphological features, and properties of paper-like films of cellulose nanofibrils. We found that removal of xylan enhances the formation of fibril networks, resulting in both stiffer gels and stronger films. However xylan also stabilizes the fibrils against flocculation. Also the history of processing of the preparations affects the results significantly.